High Temperature Vapors: Science and TechnologyHigh Temperature Vapors: Science and Technology focuses on the relationship of the basic science of high-temperature vapors to some areas of discernible practical importance in modern science and technology. The major high-temperature problem areas selected for discussion include chemical vapor transport and deposition; the vapor phase aspects of corrosion, combustion, and energy systems; and extraterrestrial high-temperature species. This book is comprised of seven chapters and begins with an introduction to the nature of the high-temperature vapor state, the scope and literature of high-temperature vapor-phase chemistry, and the role of high-temperature vapors in materials science. The discussion then turns to gas-solid reactions with vapor products; chemical vapor transport and deposition; vapor-phase aspects of corrosion at high temperature; and flames and combustion. High-temperature vapor-phase processes associated with gas turbine systems are also considered. The final chapter is devoted to the chemistry of high-temperature species in space. This monograph should serve as a valuable reference for undergraduate and graduate students, as well as scientists in fields such as chemistry, physics, materials science, and metallurgy. |
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Page 9
... composition, can in fact prove to be useful in defining phase boundaries—as was emphasized recently by Wynnyckyj (1972). Conversely, one can determine the vapor pressure or rate of vaporization for a multicomponent liquid phase using ...
... composition, can in fact prove to be useful in defining phase boundaries—as was emphasized recently by Wynnyckyj (1972). Conversely, one can determine the vapor pressure or rate of vaporization for a multicomponent liquid phase using ...
Page 10
... composition—and related properties—to the mode of vaporization. In particular, vaporization from nonstoichiometric oxides such as Fe304 (s) and W0; (s) can lead to pronounced changes in their chemical and physical nature, especially ...
... composition—and related properties—to the mode of vaporization. In particular, vaporization from nonstoichiometric oxides such as Fe304 (s) and W0; (s) can lead to pronounced changes in their chemical and physical nature, especially ...
Page 13
... composition, structure, and processing of materials to their properties and uses. From a consideration of the so-called materials cycle of: u obtaining the raw material—e.g., mining of ores; o metals extraction and refinement—i.e. ...
... composition, structure, and processing of materials to their properties and uses. From a consideration of the so-called materials cycle of: u obtaining the raw material—e.g., mining of ores; o metals extraction and refinement—i.e. ...
Page 14
... composition of stellar bodies such as hot stars, as indicated in Chapter 7, and thereby provide clues as to the primogenetic state of inorganic materials. In concluding these remarks on areas of application it may. “VD, vapor deposition ...
... composition of stellar bodies such as hot stars, as indicated in Chapter 7, and thereby provide clues as to the primogenetic state of inorganic materials. In concluding these remarks on areas of application it may. “VD, vapor deposition ...
Page 18
... composition and thermal properties of an equilibrium system may be determined from basic data. Thermodynamic tables of free energies, enthalpies, and entropies are available for many but not all reactants and products, and the following ...
... composition and thermal properties of an equilibrium system may be determined from basic data. Thermodynamic tables of free energies, enthalpies, and entropies are available for many but not all reactants and products, and the following ...
Contents
1 | |
37 | |
Chapter 3 Chemical Vapor Transport and Deposition | 91 |
Chapter 4 VaporPhase Aspects of Corrosion at High Temperature | 212 |
Chapter 5 Combustion | 226 |
Chapter 6 Energy Systems | 386 |
Chapter 7 Chemistry of High Temperature Species in Space | 427 |
References | 437 |
Index | 473 |
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addition alkali metal atoms basic bond dissociation energies bond energies Bulewicz calculated Chapter Chem chemical kinetic chemical reaction chemistry chloride coefficient combustion complex components composition concentration condensed considered corrosion defined determined discussion dissociation energies effect electron emission endothermic enthalpy entropy equilibrium constant example experimental fire flame flow fluorides flux formation free energy fuel gas—solid gases given H-atom halogen heat Hence high temperature species high temperature vapors hydroxide indicated inhibition inhibitor interaction involving ionization ions kcal kcal mol-1 kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl observed oxide oxygen Padley partial pressure phase plasma premixed present profiles radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section significant solid solubility specific spectroscopic stability sufficiently Sugden surface Table techniques thermal thermodynamic thermodynamic equilibrium tion vapor deposition vapor species vapor-phase volatile