High Temperature Vapors: Science and TechnologyHigh Temperature Vapors: Science and Technology focuses on the relationship of the basic science of high-temperature vapors to some areas of discernible practical importance in modern science and technology. The major high-temperature problem areas selected for discussion include chemical vapor transport and deposition; the vapor phase aspects of corrosion, combustion, and energy systems; and extraterrestrial high-temperature species. This book is comprised of seven chapters and begins with an introduction to the nature of the high-temperature vapor state, the scope and literature of high-temperature vapor-phase chemistry, and the role of high-temperature vapors in materials science. The discussion then turns to gas-solid reactions with vapor products; chemical vapor transport and deposition; vapor-phase aspects of corrosion at high temperature; and flames and combustion. High-temperature vapor-phase processes associated with gas turbine systems are also considered. The final chapter is devoted to the chemistry of high-temperature species in space. This monograph should serve as a valuable reference for undergraduate and graduate students, as well as scientists in fields such as chemistry, physics, materials science, and metallurgy. |
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Results 1-5 of 68
Page 3
... condensed by an increase in pressure at constant temperature, is too rigid for a discussion of the practical aspects ... condensed state; be an unsaturated inorganic vapor with no condensed state present, such as may occur, for example ...
... condensed by an increase in pressure at constant temperature, is too rigid for a discussion of the practical aspects ... condensed state; be an unsaturated inorganic vapor with no condensed state present, such as may occur, for example ...
Page 4
... Condensed Phase Vapor species Condensed phase Vapor species Condensed phase LizO Li20(c) B10; B203(c) (W03),., n = 1—5 WO,(c) Be(OH)z BeO(c) + H20 Ni + Oz NiO(c) (NaOH)2 NaOH(c) C", n = 1—5 C(c) SbS + Si Snga(c) C802, CeCi CeC2(c) Sb|Os ...
... Condensed Phase Vapor species Condensed phase Vapor species Condensed phase LizO Li20(c) B10; B203(c) (W03),., n = 1—5 WO,(c) Be(OH)z BeO(c) + H20 Ni + Oz NiO(c) (NaOH)2 NaOH(c) C", n = 1—5 C(c) SbS + Si Snga(c) C802, CeCi CeC2(c) Sb|Os ...
Page 9
... condensed phase through the basic principles of phase equilibria, e.g., see Reisman (1970). The variation of vapor pressure with temperature, or with condensed-phase composition, can in fact prove to be useful in defining phase ...
... condensed phase through the basic principles of phase equilibria, e.g., see Reisman (1970). The variation of vapor pressure with temperature, or with condensed-phase composition, can in fact prove to be useful in defining phase ...
Page 10
... condensed solid state via thermodynamic relations such as the Born—Haber, e.g., see Gutmann and Mayer (1972), and related cycles, e.g., see Oshcherin (1971). For example, with the defect structure model of zirconium trihalide ...
... condensed solid state via thermodynamic relations such as the Born—Haber, e.g., see Gutmann and Mayer (1972), and related cycles, e.g., see Oshcherin (1971). For example, with the defect structure model of zirconium trihalide ...
Page 11
... condensed—phase thermodynamic properties, as was shown by Brewer (1971) for the lanthanide and actinide metals. The nature of the chemical bond in polyatomic vapor-phase species should also be relatable to the condensed-phase stability ...
... condensed—phase thermodynamic properties, as was shown by Brewer (1971) for the lanthanide and actinide metals. The nature of the chemical bond in polyatomic vapor-phase species should also be relatable to the condensed-phase stability ...
Contents
1 | |
37 | |
Chapter 3 Chemical Vapor Transport and Deposition | 91 |
Chapter 4 VaporPhase Aspects of Corrosion at High Temperature | 212 |
Chapter 5 Combustion | 226 |
Chapter 6 Energy Systems | 386 |
Chapter 7 Chemistry of High Temperature Species in Space | 427 |
References | 437 |
Index | 473 |
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addition alkali metal atoms basic bond dissociation energies bond energies Bulewicz calculated Chapter Chem chemical kinetic chemical reaction chemistry chloride coefficient combustion complex components composition concentration condensed considered corrosion defined determined discussion dissociation energies effect electron emission endothermic enthalpy entropy equilibrium constant example experimental fire flame flow fluorides flux formation free energy fuel gas—solid gases given H-atom halogen heat Hence high temperature species high temperature vapors hydroxide indicated inhibition inhibitor interaction involving ionization ions kcal kcal mol-1 kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl observed oxide oxygen Padley partial pressure phase plasma premixed present profiles radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section significant solid solubility specific spectroscopic stability sufficiently Sugden surface Table techniques thermal thermodynamic thermodynamic equilibrium tion vapor deposition vapor species vapor-phase volatile