High Temperature Vapors: Science and TechnologyHigh Temperature Vapors: Science and Technology focuses on the relationship of the basic science of high-temperature vapors to some areas of discernible practical importance in modern science and technology. The major high-temperature problem areas selected for discussion include chemical vapor transport and deposition; the vapor phase aspects of corrosion, combustion, and energy systems; and extraterrestrial high-temperature species. This book is comprised of seven chapters and begins with an introduction to the nature of the high-temperature vapor state, the scope and literature of high-temperature vapor-phase chemistry, and the role of high-temperature vapors in materials science. The discussion then turns to gas-solid reactions with vapor products; chemical vapor transport and deposition; vapor-phase aspects of corrosion at high temperature; and flames and combustion. High-temperature vapor-phase processes associated with gas turbine systems are also considered. The final chapter is devoted to the chemistry of high-temperature species in space. This monograph should serve as a valuable reference for undergraduate and graduate students, as well as scientists in fields such as chemistry, physics, materials science, and metallurgy. |
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Page 1
... kinetic, and transport properties.'[ Application of the basic principles of thermodynamics, kinetics, and gas dynamics permits a rigorous connection to be made between the micro—i.e., molecular—structure of high temperature vapors and ...
... kinetic, and transport properties.'[ Application of the basic principles of thermodynamics, kinetics, and gas dynamics permits a rigorous connection to be made between the micro—i.e., molecular—structure of high temperature vapors and ...
Page 2
... kinetic energy of a propellant gas, because of the heat-Sink effect which results from the distribution of energy among the various internal degrees of freedom, e.g., see Holzmann (1969). Another example, from the area of combustion, is ...
... kinetic energy of a propellant gas, because of the heat-Sink effect which results from the distribution of energy among the various internal degrees of freedom, e.g., see Holzmann (1969). Another example, from the area of combustion, is ...
Page 3
... ions, and electrons, which result from thermal—Le, equilibrium—or kinetic processes at high temperature; TABLE 1.1 Representative Examples of High Temperature Species— in the I. The Nature of High Temperature Vapors 3.
... ions, and electrons, which result from thermal—Le, equilibrium—or kinetic processes at high temperature; TABLE 1.1 Representative Examples of High Temperature Species— in the I. The Nature of High Temperature Vapors 3.
Page 6
... kinetics. These areas have received considerable attention in subsequent years and will be discussed further in later chapters. 1959-1964 The fundamental physicochemical aspects of high temperature were reviewed in the book edited by ...
... kinetics. These areas have received considerable attention in subsequent years and will be discussed further in later chapters. 1959-1964 The fundamental physicochemical aspects of high temperature were reviewed in the book edited by ...
Page 7
Science and Technology John Hastie. dynamics, kinetics, chemical bonding, gas—metal reactions, and materials requirements for ... Kinetic data relating to molecular reaction rates, vaporization coefficients, gas— solid reactions, and ...
Science and Technology John Hastie. dynamics, kinetics, chemical bonding, gas—metal reactions, and materials requirements for ... Kinetic data relating to molecular reaction rates, vaporization coefficients, gas— solid reactions, and ...
Contents
1 | |
37 | |
Chapter 3 Chemical Vapor Transport and Deposition | 91 |
Chapter 4 VaporPhase Aspects of Corrosion at High Temperature | 212 |
Chapter 5 Combustion | 226 |
Chapter 6 Energy Systems | 386 |
Chapter 7 Chemistry of High Temperature Species in Space | 427 |
References | 437 |
Index | 473 |
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addition alkali metal atoms basic bond dissociation energies bond energies Bulewicz calculated Chapter Chem chemical kinetic chemical reaction chemistry chloride coefficient combustion complex components composition concentration condensed considered corrosion defined determined discussion dissociation energies effect electron emission endothermic enthalpy entropy equilibrium constant example experimental fire flame flow fluorides flux formation free energy fuel gas—solid gases given H-atom halogen heat Hence high temperature species high temperature vapors hydroxide indicated inhibition inhibitor interaction involving ionization ions kcal kcal mol-1 kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl observed oxide oxygen Padley partial pressure phase plasma premixed present profiles radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section significant solid solubility specific spectroscopic stability sufficiently Sugden surface Table techniques thermal thermodynamic thermodynamic equilibrium tion vapor deposition vapor species vapor-phase volatile