High Temperature Vapors: Science and TechnologyHigh Temperature Vapors: Science and Technology focuses on the relationship of the basic science of high-temperature vapors to some areas of discernible practical importance in modern science and technology. The major high-temperature problem areas selected for discussion include chemical vapor transport and deposition; the vapor phase aspects of corrosion, combustion, and energy systems; and extraterrestrial high-temperature species. This book is comprised of seven chapters and begins with an introduction to the nature of the high-temperature vapor state, the scope and literature of high-temperature vapor-phase chemistry, and the role of high-temperature vapors in materials science. The discussion then turns to gas-solid reactions with vapor products; chemical vapor transport and deposition; vapor-phase aspects of corrosion at high temperature; and flames and combustion. High-temperature vapor-phase processes associated with gas turbine systems are also considered. The final chapter is devoted to the chemistry of high-temperature species in space. This monograph should serve as a valuable reference for undergraduate and graduate students, as well as scientists in fields such as chemistry, physics, materials science, and metallurgy. |
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Page vi
... Metal Halide Lamps 203 4- Vapor-Phase Aspects of Corrosion at High Temperature I. Introduction 212 II. Corrosion ... Metals 366' IX. Theoretical Performance of Chemical Rocket Engines 371 6 Energy Systems I. Introduction 386 II. Thermal ...
... Metal Halide Lamps 203 4- Vapor-Phase Aspects of Corrosion at High Temperature I. Introduction 212 II. Corrosion ... Metals 366' IX. Theoretical Performance of Chemical Rocket Engines 371 6 Energy Systems I. Introduction 386 II. Thermal ...
Page 55
... metal halide lamps (see Chapter 3), the in situ generation of volatile metal halide flame inhibitors (see Chapter 5), and other vapor transport applications as discussed throughout Chapter 3. The following discussion serves to ...
... metal halide lamps (see Chapter 3), the in situ generation of volatile metal halide flame inhibitors (see Chapter 5), and other vapor transport applications as discussed throughout Chapter 3. The following discussion serves to ...
Page 56
... halide phases may form. For example, at relatively low temperatures, i.e. ... metal chlorides during chlorination reactions. The rates of chlorination can ... metal halide vapor boundary layer is rate controlling. At lower temperatures ...
... halide phases may form. For example, at relatively low temperatures, i.e. ... metal chlorides during chlorination reactions. The rates of chlorination can ... metal halide vapor boundary layer is rate controlling. At lower temperatures ...
Page 68
... metal-hydroxyl type bonds is the only reasonable explanation in this case. 3. Summary of “Known” Hydroxide Species ... halide, HF or HCl. These halides can noticeably influence the formation of metal hydroxides, and it is important to ...
... metal-hydroxyl type bonds is the only reasonable explanation in this case. 3. Summary of “Known” Hydroxide Species ... halide, HF or HCl. These halides can noticeably influence the formation of metal hydroxides, and it is important to ...
Page 71
... metal hydroxide and halide bond dissociation energies, i.e., see Chapter 5, Section. II.K.5,. DM_()H 2 0.8DM_F. Therefore, the reaction enthalpy is AH3 = 0.4DM_F — 34 kcal mol". Obviously, the production of M(OH)2 relative to MX2 is ...
... metal hydroxide and halide bond dissociation energies, i.e., see Chapter 5, Section. II.K.5,. DM_()H 2 0.8DM_F. Therefore, the reaction enthalpy is AH3 = 0.4DM_F — 34 kcal mol". Obviously, the production of M(OH)2 relative to MX2 is ...
Contents
1 | |
37 | |
Chapter 3 Chemical Vapor Transport and Deposition | 91 |
Chapter 4 VaporPhase Aspects of Corrosion at High Temperature | 212 |
Chapter 5 Combustion | 226 |
Chapter 6 Energy Systems | 386 |
Chapter 7 Chemistry of High Temperature Species in Space | 427 |
References | 437 |
Index | 473 |
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addition alkali metal atoms basic bond dissociation energies bond energies Bulewicz calculated Chapter Chem chemical kinetic chemical reaction chemistry chloride coefficient combustion complex components composition concentration condensed considered corrosion defined determined discussion dissociation energies effect electron emission endothermic enthalpy entropy equilibrium constant example experimental fire flame flow fluorides flux formation free energy fuel gas—solid gases given H-atom halogen heat Hence high temperature species high temperature vapors hydroxide indicated inhibition inhibitor interaction involving ionization ions kcal kcal mol-1 kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl observed oxide oxygen Padley partial pressure phase plasma premixed present profiles radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section significant solid solubility specific spectroscopic stability sufficiently Sugden surface Table techniques thermal thermodynamic thermodynamic equilibrium tion vapor deposition vapor species vapor-phase volatile