Conjugated Conducting Polymers |
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Page 64
197 ] . d ) Numerical Many - Body Methods for Finite Clusters To study the full
many - body problem in correlated electron theories requires , as noted above ,
dealing with matrices that grow in size exponentially with the number of sites .
Hence ...
197 ] . d ) Numerical Many - Body Methods for Finite Clusters To study the full
many - body problem in correlated electron theories requires , as noted above ,
dealing with matrices that grow in size exponentially with the number of sites .
Hence ...
Page 83
Thirdly , independent of the relative strengths of the various interactions , one can
generally classify eigenstates of the finite , even , linear polyenes as symmetric (
A ) or antisymmetric ( B ) with respect to the two - fold axis perpendicular to the ...
Thirdly , independent of the relative strengths of the various interactions , one can
generally classify eigenstates of the finite , even , linear polyenes as symmetric (
A ) or antisymmetric ( B ) with respect to the two - fold axis perpendicular to the ...
Page 87
neither finite size effects nor sp - sp2 site energy differences alter this conclusion [
2 . 266 ] . Thus one is left with the task of explaining simultaneously both the
smaller gaps of the oligomers of PDAs compared to the finite polyenes and the ...
neither finite size effects nor sp - sp2 site energy differences alter this conclusion [
2 . 266 ] . Thus one is left with the task of explaining simultaneously both the
smaller gaps of the oligomers of PDAs compared to the finite polyenes and the ...
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Contents
Introduction | 1 |
An Overview of the Theory of rConjugated Polymers | 7 |
IndependentElectron | 17 |
Copyright | |
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absorption addition applied approach approximation atoms band behaviour bipolarons bond bond alternation calculations carriers chain charged chemical concentration conductivity configuration conjugated polymers correlation corresponding Coulomb Coulomb interactions coupling decreases defects density dependence described determined dimerization discussed dopant doping effects electron electron-electron electron-phonon ENDOR energy excitations expected experimental experiments field finite frequency function give ground Hamiltonian hopping Hubbard hyperfine important increase indicated interactions interpretation involving lattice leads length Lett limit magnetic materials measurements metallic methods modes motion neutral nuclear observed obtained one-dimensional optical pair parameter peak phonon Phys physical polarons polyacetylene polyenes polymers position properties range relaxation resonance respect samples Sect shift shown shows similar single Solid soliton spectra spectrum spin structure studies symmetry Synth temperature theoretical theory trans-(CH transition units valence values whereas