Conjugated Conducting Polymers |
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The conductivity of semiconducting polymers was shown to become metallic if
materials with extended re - electron systems were doped with strong oxidizing or
reducing agents . Indeed , it was experimentally demonstrated that the ...
The conductivity of semiconducting polymers was shown to become metallic if
materials with extended re - electron systems were doped with strong oxidizing or
reducing agents . Indeed , it was experimentally demonstrated that the ...
Page 164
4 The Semiconductor - Metal Transition and the Metallic State In the last section
the steep conductivity increase , occurring around a doping level of 0 . 001 in all
the materials studied , was discussed . Although the conductivities obtained are ...
4 The Semiconductor - Metal Transition and the Metallic State In the last section
the steep conductivity increase , occurring around a doping level of 0 . 001 in all
the materials studied , was discussed . Although the conductivities obtained are ...
Page 169
... approximately in proportion to the amount of doping ( protonation in this case )
[ 3 . 93 ] . From this it is concluded that heavily doped polyaniline is a two - phase
material , consisting of metallic , fully protonated regions and insulating more or ...
... approximately in proportion to the amount of doping ( protonation in this case )
[ 3 . 93 ] . From this it is concluded that heavily doped polyaniline is a two - phase
material , consisting of metallic , fully protonated regions and insulating more or ...
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Contents
Introduction | 1 |
An Overview of the Theory of rConjugated Polymers | 7 |
IndependentElectron | 17 |
Copyright | |
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absorption addition applied approach approximation atoms band behaviour bipolarons bond bond alternation calculations carriers chain charged chemical concentration conductivity configuration conjugated polymers correlation corresponding Coulomb Coulomb interactions coupling decreases defects density dependence described determined dimerization discussed dopant doping effects electron electron-electron electron-phonon ENDOR energy excitations expected experimental experiments field finite frequency function give ground Hamiltonian hopping Hubbard hyperfine important increase indicated interactions interpretation involving lattice leads length Lett limit magnetic materials measurements metallic methods modes motion neutral nuclear observed obtained one-dimensional optical pair parameter peak phonon Phys physical polarons polyacetylene polyenes polymers position properties range relaxation resonance respect samples Sect shift shown shows similar single Solid soliton spectra spectrum spin structure studies symmetry Synth temperature theoretical theory trans-(CH transition units valence values whereas