Properties of Liquids and SolutionsProperties of Liquids and Solutions Second Edition J.N. Murrell A.D. Jenkins University of Sussex, Brighton, UK Properties of Liquids and Solutions, Second edition, is a fully revised and updated edition of this popular text, providing a broad coverage of the physics and chemistry of the liquid state. In recent years there have been great developments in the understanding of intermolecular potentials and computer simulation of bulk properties, and these advances are reflected in the new material in this edition. Properties of Liquids and Solutions continues to bring together an up-to-date account of advances, as well as providing essential background information, in the study of the liquid state. Properties of Liquids and Solutions will continue to be an indispensable teaching text for lecturers and students in chemistry, biochemistry, chemical physics, materials science and environmental science. |
Contents
THERMODYNAMIC PROPERTIES OF PURE LIQUIDS | 4 |
INTERMOLECULAR FORCES | 15 |
THEORIES AND MODELS OF THE LIQUID STATE | 40 |
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acid activity coefficient approximately atoms behaviour benzene boiling point calculated cell Chapter charge Chem chemical potential colloids component composition concentration constant critical point crystal deduced defined density depends diffraction dipole dispersion energy distance electrons electrostatic energy enthalpy entropy equation equilibrium example expression fluid free energy gases Gibbs Gibbs free energy H₂O hence Henry's law hydration hydrogen bond ideal induction energy integral interaction interface intermolecular energy intermolecular potential ionic ions kJ mol-¹ lattice liquid phase London long-range macroscopic measured melting point mesophase miscible mixture molar mass molar volume mole fraction molecular multipole expansion non-ideal obtained pair potential parameters particles phase diagram Phys polar polymer polymer molecule properties proton quantity radial distribution function repulsive RT ln shown in Figure shows solid solubility solvent species structure supercritical supercritical fluids surface temperature theory thermodynamic vapour pressure viscosity Waals water molecules zero