Self and Probe Diffusion of Polyelectrolyte in Complex Media

added salt blobs Chapter Chem CKBr conformation counter-ion Cp,min crystallites Dc,fast decreases degree of quaternization dependence of Ds diffusion coefficient dilute solution dynamic light scattering dynamics effect electrostatic Equation ethyl bromide experimental Figure forced Rayleigh scattering FRS measurements gel temperature gelatin gelatin gel gelatin solution Gennes grating hydrophobic interactions increases Joanny and Leibler Khokhlov laser Macromolecules matrix micelle micelle formation molecular weight exponent monomers NaCl neutral polymers neutral regime Odijk P2VP P2VP-EtBr P2VP-EtBr in PAAm PAAm PAAm gel PAAm solutions persistence length photomultiplier Phys poly(2-vinyl pyridine poly(2-vinyl pyridine)-ethyl bromide poly(styrene sulfonate polyelectrolyte polyelectrolyte solution polyion polymer chains polymer solution polymerization predicted probe pyridine quasielastic light scattering quaternization degree Rayleigh scattering reptation model sample self-diffusion coefficient semi-dilute regime solutions and gels solvent technique theories thesis tracer diffusion coefficient transient vector viscometry viscosity