Mechanism and Theory in Organic Chemistry |
From inside the book
Results 1-3 of 75
Page 235
... reactants . Appendix 2 to this chapter gives a derivation that generalizes this argument and shows that the isotope effect is more closely approximated by Equation 2.153 . kH - kн ≈ й exp ( − ( 1⁄4 , н — U , D ) : ] Í exp [ + ( U ; H ...
... reactants . Appendix 2 to this chapter gives a derivation that generalizes this argument and shows that the isotope effect is more closely approximated by Equation 2.153 . kH - kн ≈ й exp ( − ( 1⁄4 , н — U , D ) : ] Í exp [ + ( U ; H ...
Page 237
... reactants . If the transition state is highly symmetric , оо A H B 90 so that the AH and the HB force constants are equal , this stretch will involve only A and B moving in and out together , with no motion of the H ( or D ) . The ...
... reactants . If the transition state is highly symmetric , оо A H B 90 so that the AH and the HB force constants are equal , this stretch will involve only A and B moving in and out together , with no motion of the H ( or D ) . The ...
Page 350
... Reactants are at the back left corner and products are at the front right corner . The reaction coordinate is the heavy curved line joining the reactants and products ; its projection on the horizontal plane is the heavy straight line ...
... Reactants are at the back left corner and products are at the front right corner . The reaction coordinate is the heavy curved line joining the reactants and products ; its projection on the horizontal plane is the heavy straight line ...
Contents
THE COVALENT BOND | 1 |
Molecular Orbital Theory | 87 |
SOME FUNDAMENTALS OF PHYSICAL | 127 |
Copyright | |
13 other sections not shown
Other editions - View all
Common terms and phrases
acetic acid-base acidity function addition alkene alkyl American Chemical Society anion Arnett aromatic atomic orbitals atoms base Brønsted C-X bond carbanion carbon carbonyl catalysis cation CH₂ CH3 CH3 charge Chem coefficients compounds configuration conjugate conjugate acid Copyright correlation delocalized diagram dissociation double bond electron electrophilic equilibrium constant example Figure free energy gas-phase H H H H₂O HOMO hydrogen interaction intermediate ion pair ionization isotope effect Jencks k₁ kcal kcal mol¹ kinetic kJ mol¯¹ leaving group LUMO mechanism methyl mol-¹ molecular orbitals molecule nucleophile occur Olah Organic Chemistry oxygen parameters phenyl Phys potential energy proton proton transfer racemic rate constant rate-determining ratio reactants reaction coordinate reactive rearrangement relative resonance ring Scheme Schleyer shown in Equation solution solvation solvent solvolysis stabilization steric Streitwieser structure substituents substitution substrate symmetry Table tion tosylate transition values vibrational Wiley Winstein York