Tautomerism: Concepts and Applications in Science and TechnologyReflecting the substantially increased interest in tautomerism, this book demonstrates the transformation of fundamental knowledge into novel concepts and the latest applications. Each chapter introduces the theoretical background, before reviewing and critically discussing the experimental techniques and corresponding applications. Special emphasis is placed on tautomerism under unusual conditions, such as in supramolecular solids and at surfaces, displaying the wide scope between basic research and timely applications. |
Contents
Cover | |
Preface | |
Triage for Tautomers The Choice between | |
Derivatives of Pyrrole Furan and Thiazole | |
Methods to Distinguish Tautomeric Cases | |
ElectronTransferInduced Tautomerizations | |
The Fault Line in Prototropic Tautomerism | |
Theoretical Consideration of InSolution | |
Tautomerism in Oxoporphyrinogens | |
EnolimineKetoenamine Tautomerism | |
Acknowledgments | |
Tautomerizable Azophenol Dyes | |
Controlled Tautomerism Is It Possible? | |
References | |
Supramolecular Control over Tautomerism | |
Examples from Organic | |
Direct Observation and Control of Single | |
References | |
Reorganization of the Environment | |
Other editions - View all
Tautomerism: Concepts and Applications in Science and Technology Liudmil Antonov Limited preview - 2016 |
Tautomerism: Concepts and Applications in Science and Technology Liudmil Antonov Limited preview - 2016 |
Common terms and phrases
absorption acceptor acetonitrile acid adatom amidines Antonov aqueous solution azophenols calculations carboxylic carboxylic acid Chem chemical shifts Chemical structure Chemistry chemosensor cocrystals complex compounds computational conformation Copyright corresponding crystal structure Denisov derivatives dimers dipole donor Dubonosov electron Elguero enol enol form enol radical cation ethanol experimental fluorescence formation free energy functional gas phase geometries H3TBA Heterocycl hydrogen bond hyperpolarizability interactions intramolecular intramolecular hydrogen bond Katritzky kcal kcal mol−1 keto keto form kinetic Lett Limbach methods Minkin Nagy neutral nonlinear optical observed photochromic Phys piroxicam pKa values polar polymorphs porphycene molecule proton transfer pyrazinacenes pyridine radical cation ratio reaction Reproduced resonance ring Scheme Schiff bases solid solvation solvent spectra spectroscopy stabilization STM images substituents supramolecular synthons tautomer tautomeric tautomeric equilibrium tautomeric forms temperature theoretical thermal isomerization tunneling zwitterionic