Physical Properties of Polymeric GelsJ. P. Cohen Addad This book emphasizes the relationship between the microscopic structure of gels and their macroscopic behaviour. Deals with organic polymeric gels, focusing on experimental methods which have only recently been introduced to study both reversible and irreversible gels. It introduce the reader with to theory and practice of physics as applied to the study of characteristics of polymeric gels and offers several clearly described basic approaches to experimental investigations into gel properties. An outstanding resource on experimental advances and modern interpretations of polymeric gel properties written by prominent experts in the field. |
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Page 143
... idealized gels , according to theories 160 160 162 164 166 166 168 170 5.3.1 Low scattering vector limit 171 • gel 5.3.1.1 ( 0 ) for idealized gels at maximum swelling versus Isol ( 0 ) for solutions . . 174 5.3.1.2 Igel ( 0 ) for ...
... idealized gels , according to theories 160 160 162 164 166 166 168 170 5.3.1 Low scattering vector limit 171 • gel 5.3.1.1 ( 0 ) for idealized gels at maximum swelling versus Isol ( 0 ) for solutions . . 174 5.3.1.2 Igel ( 0 ) for ...
Page 171
... idealized gels ' such networks filled with solvent , in which no correlations are believed to exist beyond the scale of the mesh , and which fluctuate locally because of thermal agitation . The question of the structure factor of such ...
... idealized gels ' such networks filled with solvent , in which no correlations are believed to exist beyond the scale of the mesh , and which fluctuate locally because of thermal agitation . The question of the structure factor of such ...
Page 174
... idealized gels at maximum swelling versus Iso1 ( 0 ) for solutions sol OS sol sol sol OS Still assuming that П ( 4 ) can be represented by a ... idealized gels at incomplete 174 STRUCTURE OF GELS INVESTIGATED BY STATIC SCATTERING TECHNIQUES.
... idealized gels at maximum swelling versus Iso1 ( 0 ) for solutions sol OS sol sol sol OS Still assuming that П ( 4 ) can be represented by a ... idealized gels at incomplete 174 STRUCTURE OF GELS INVESTIGATED BY STATIC SCATTERING TECHNIQUES.
Contents
Semidilute Polymer Solutions | 1 |
Properties of Polyelectrolyte Gels | 19 |
NMR and Statistical Structures of Gels | 39 |
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Common terms and phrases
average Bastide behaviour Boué branched polymers Candau chain segments Chem chemical clusters Cohen Addad concentration fluctuations correlation length corresponding counterions crosslinking density Daoud deformation degree of swelling dependence dilute dynamics effect elastic elastic modulus excluded volume experimental exponent values Figure Flory Flory-Huggins theory fluctuations of polymer fractal dimension free energy frozen blobs function Gaussian Geissler Gennes heterogeneities idealized gels interactions larger Leibler length scales light scattering low q Macromolecules maximum swelling mean field measured mesh molecular weight molecules monomeric units monomers network chain network structure neutron scattering number of monomers observed obtained osmotic pressure PAAM parameter percolation Phys polyelectrolyte polymer chains polymer concentration polymer solutions polymeric polymeric gels polystyrene properties quenched fluctuations random relaxation sample scattering experiments scattering intensity semi-dilute solution shear modulus skeletal bonds solvent static stretching structure factor swelling degree swollen theory uniaxial vector volume fraction wave vector