Physical Properties of Polymeric GelsJ. P. Cohen Addad This book emphasizes the relationship between the microscopic structure of gels and their macroscopic behaviour. Deals with organic polymeric gels, focusing on experimental methods which have only recently been introduced to study both reversible and irreversible gels. It introduce the reader with to theory and practice of physics as applied to the study of characteristics of polymeric gels and offers several clearly described basic approaches to experimental investigations into gel properties. An outstanding resource on experimental advances and modern interpretations of polymeric gel properties written by prominent experts in the field. |
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Page 7
... length scales larger than , the chains retain Gaussian statistics . 1.3 Scaling theory of semi - dilute solutions The Flory - Huggins theory is a mean field model which assumes that the polymer chains are Gaussian at all length scales ...
... length scales larger than , the chains retain Gaussian statistics . 1.3 Scaling theory of semi - dilute solutions The Flory - Huggins theory is a mean field model which assumes that the polymer chains are Gaussian at all length scales ...
Page 11
... length scales the polymer chains are not swollen . We now group the monomers into thermal blobs , each containing g , monomers ; the interaction free energy between thermal blobs increases with the number of monomers in the blob and we ...
... length scales the polymer chains are not swollen . We now group the monomers into thermal blobs , each containing g , monomers ; the interaction free energy between thermal blobs increases with the number of monomers in the blob and we ...
Page 157
... length scales larger than . In good solvent , is also assumed to represent approximately the length scale beyond which the chains are interpenetrated . In other words , it means that the correlation length is roughly equal to the ...
... length scales larger than . In good solvent , is also assumed to represent approximately the length scale beyond which the chains are interpenetrated . In other words , it means that the correlation length is roughly equal to the ...
Contents
Semidilute Polymer Solutions | 1 |
Properties of Polyelectrolyte Gels | 19 |
NMR and Statistical Structures of Gels | 39 |
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Common terms and phrases
average Bastide behaviour Boué branched polymers Candau chain segments Chem chemical clusters Cohen Addad concentration fluctuations correlation length corresponding counterions crosslinking density Daoud deformation degree of swelling dependence dilute dynamics effect elastic elastic modulus excluded volume experimental exponent values Figure Flory Flory-Huggins theory fluctuations of polymer fractal dimension free energy frozen blobs function Gaussian Geissler Gennes heterogeneities idealized gels interactions larger Leibler length scales light scattering low q Macromolecules maximum swelling mean field measured mesh molecular weight molecules monomeric units monomers network chain network structure neutron scattering number of monomers observed obtained osmotic pressure PAAM parameter percolation Phys polyelectrolyte polymer chains polymer concentration polymer solutions polymeric polymeric gels polystyrene properties quenched fluctuations random relaxation sample scattering experiments scattering intensity semi-dilute solution shear modulus skeletal bonds solvent static stretching structure factor swelling degree swollen theory uniaxial vector volume fraction wave vector