Physical Properties of Polymeric GelsJ. P. Cohen Addad This book emphasizes the relationship between the microscopic structure of gels and their macroscopic behaviour. Deals with organic polymeric gels, focusing on experimental methods which have only recently been introduced to study both reversible and irreversible gels. It introduce the reader with to theory and practice of physics as applied to the study of characteristics of polymeric gels and offers several clearly described basic approaches to experimental investigations into gel properties. An outstanding resource on experimental advances and modern interpretations of polymeric gel properties written by prominent experts in the field. |
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Page 13
... monomer depends solely on the velocity of that monomer independently of the other monomers . The total friction on a chain Sch is then proportional to the number of monomers = Sch = NS ( 29 ) The diffusion constant of a chain is related ...
... monomer depends solely on the velocity of that monomer independently of the other monomers . The total friction on a chain Sch is then proportional to the number of monomers = Sch = NS ( 29 ) The diffusion constant of a chain is related ...
Page 90
J. P. Cohen Addad. a function of p and f . The total number of molecules at a given time is equal to the number of monomers ( which corresponds to the number of molecules in the medium at time zero ) minus the number of chemical links so ...
J. P. Cohen Addad. a function of p and f . The total number of molecules at a given time is equal to the number of monomers ( which corresponds to the number of molecules in the medium at time zero ) minus the number of chemical links so ...
Page 114
... monomers belonging either to the same polymer or to different polymers respectively . In the case of polymer ... number of monomers per molecule multiplied by the number n of molecules in the solution . At length scale q1 between the ...
... monomers belonging either to the same polymer or to different polymers respectively . In the case of polymer ... number of monomers per molecule multiplied by the number n of molecules in the solution . At length scale q1 between the ...
Contents
Semidilute Polymer Solutions | 1 |
Properties of Polyelectrolyte Gels | 19 |
NMR and Statistical Structures of Gels | 39 |
Copyright | |
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Common terms and phrases
average Bastide behaviour Boué branched polymers Candau chain segments Chem chemical clusters Cohen Addad concentration fluctuations correlation length corresponding counterions crosslinking density Daoud deformation degree of swelling dependence dilute dynamics effect elastic elastic modulus excluded volume experimental exponent values Figure Flory Flory-Huggins theory fluctuations of polymer fractal dimension free energy frozen blobs function Gaussian Geissler Gennes heterogeneities idealized gels interactions larger Leibler length scales light scattering low q Macromolecules maximum swelling mean field measured mesh molecular weight molecules monomeric units monomers network chain network structure neutron scattering number of monomers observed obtained osmotic pressure PAAM parameter percolation Phys polyelectrolyte polymer chains polymer concentration polymer solutions polymeric polymeric gels polystyrene properties quenched fluctuations random relaxation sample scattering experiments scattering intensity semi-dilute solution shear modulus skeletal bonds solvent static stretching structure factor swelling degree swollen theory uniaxial vector volume fraction wave vector