Conjugated Polymers: The Novel Science and Technology of Highly Conducting and Nonlinear Optically Active MaterialsJ.L. Brédas, R. Silbey CONJUGATED POLYMERS: THE IMTERPLAY BETWEEN SYNTHESIS, 1 STRUCTURE, AND PROPERTIES C. B. GORMAN and R. H. GRUBBS 1. Introduction 2 2. Structural Features of Conjuqated. Polyaers 3 3. Polymer Synthesis: Basic Methods 4 3. 1 Step-Growth Polymerization 5 3. 2 Chain-Growth Polymerization 6 3. 3 Rinq-Openinq Polymerization 8 4. Direct Synthetic Methods 8 4. 1 Electrochemical Synthesis 9 4. 2 Synthesis by Step-Growth Polymerization 11 4. 2. 1 Polyaniline (PAN) 11 4. 2. 2 Poly(Phenylene Sulfide) 12 4. 2. 3 Poly thiophene and its Derivatives 13 4. 2. 4 Other 5-membered Heterocyclic 16 Derivatives 4. 2. 5 Polyparaphenylene (PPP) 17 4. 2. 6 Polysilanes 18 4. 2. 7 Polymers of Phthalocyanines 19 4. 2. 8 Other Conjugated Metal Coordination 20 Polymers 4. 2. 9 Ladder Polymers 21 4. 3 The Unusual Topochemical Polymerization to 23 form Polydiacetylenes 4. 4 Chain-Growth Polymerizations 24 4. 4. 1 Polyacetylene via Ziegler-Natta 24 Polymerization 4. 4. 2 Ring-Opening Metathesis Polymerization 26 Routes to Polyacetylenes 5. Polymers fro. precursors 27 5. 1 Polyparaphenylene (PPP) 27 5. 2 Poly(Phenylene Vinylene) (PPV) and Other 28 Vinylene Polymers 5. 3 Precursors to Polyacetylene 29 6. Extentions of these Methods in the Synthesis of 31 .saall-Bandqap. Pplymers 7. Conjuqated. Polymer Matrices 33 8. Conclusions and Caveats 35 Acknowled. qements 36 References 36 vi TABLE OF CONTENTS PROPERTIES OF HIGHLY CONDUCTIHG POLYACETYLEHE 49 Th. SCHIMMEL, D. GLASER, M. SCHWOERER AND H. NAARMANN 1. Introduction 50 2. SBIlpie Synthesis, lIorphology and Properties 52 2." |
Contents
I | 1 |
II | 2 |
III | 3 |
IV | 4 |
V | 5 |
VI | 6 |
VII | 8 |
IX | 9 |
CLXIV | 296 |
CLXV | 297 |
CLXVI | 302 |
CLXVII | 306 |
CLXIX | 308 |
CLXX | 312 |
CLXXII | 315 |
CLXXIV | 317 |
X | 11 |
XII | 12 |
XIII | 13 |
XIV | 16 |
XV | 17 |
XVI | 18 |
XVII | 19 |
XVIII | 20 |
XIX | 21 |
XX | 23 |
XXI | 24 |
XXIII | 27 |
XXV | 28 |
XXVI | 29 |
XXVII | 31 |
XXVIII | 33 |
XXIX | 35 |
XXX | 36 |
XXXII | 49 |
XXXIII | 50 |
XXXIV | 52 |
XXXVI | 53 |
XXXVII | 55 |
XXXVIII | 56 |
XXXIX | 57 |
XL | 58 |
XLI | 59 |
XLII | 60 |
XLIII | 61 |
XLIV | 62 |
XLV | 64 |
XLVI | 66 |
XLVII | 68 |
XLIX | 69 |
L | 70 |
LI | 72 |
LII | 76 |
LIV | 77 |
LV | 79 |
LVIII | 81 |
LIX | 82 |
LX | 84 |
LXI | 85 |
LXII | 87 |
LXIII | 88 |
LXIV | 93 |
LXV | 94 |
LXVI | 96 |
LXVIII | 97 |
LXIX | 98 |
LXX | 100 |
LXXI | 102 |
LXXII | 105 |
LXXIII | 106 |
LXXIV | 108 |
LXXV | 109 |
LXXVI | 113 |
LXXVIII | 114 |
LXXIX | 118 |
LXXX | 122 |
LXXXI | 123 |
LXXXIII | 124 |
LXXXV | 125 |
LXXXVI | 128 |
LXXXVII | 130 |
LXXXVIII | 133 |
LXXXIX | 134 |
XC | 136 |
XCI | 137 |
XCII | 138 |
XCIII | 141 |
XCV | 142 |
XCVI | 146 |
XCVIII | 149 |
XCIX | 172 |
C | 173 |
CI | 174 |
CII | 178 |
CIII | 179 |
CIV | 181 |
CV | 184 |
CVI | 185 |
CVIII | 188 |
CX | 192 |
CXI | 194 |
CXII | 196 |
CXIII | 197 |
CXV | 199 |
CXVI | 201 |
CXVII | 203 |
CXVIII | 204 |
CXIX | 211 |
CXXI | 213 |
CXXII | 216 |
CXXIII | 220 |
CXXV | 222 |
CXXVI | 223 |
CXXVII | 224 |
CXXX | 229 |
CXXXII | 231 |
CXXXIV | 235 |
CXXXV | 237 |
CXXXVI | 239 |
CXXXVII | 240 |
CXXXVIII | 241 |
CXXXIX | 243 |
CXL | 245 |
CXLI | 247 |
CXLII | 249 |
CXLIII | 253 |
CXLIV | 254 |
CXLV | 257 |
CXLVI | 259 |
CXLVII | 260 |
CXLVIII | 261 |
CXLIX | 262 |
CL | 263 |
CLI | 264 |
CLII | 265 |
CLIII | 266 |
CLIV | 268 |
CLV | 269 |
CLVI | 274 |
CLVII | 276 |
CLVIII | 281 |
CLIX | 283 |
CLXI | 286 |
CLXII | 288 |
CLXIII | 294 |
CLXXV | 318 |
CLXXVI | 320 |
CLXXVII | 321 |
CLXXVIII | 322 |
CLXXIX | 323 |
CLXXX | 324 |
CLXXXII | 327 |
CLXXXIII | 329 |
CLXXXIV | 332 |
CLXXXV | 337 |
CLXXXVI | 338 |
CLXXXVII | 339 |
CLXXXVIII | 343 |
CXC | 345 |
CXCI | 347 |
CXCII | 350 |
CXCIII | 351 |
CXCIV | 352 |
CXCV | 353 |
CXCVII | 354 |
CXCVIII | 363 |
CC | 364 |
CCI | 376 |
CCII | 377 |
CCIII | 381 |
CCV | 387 |
CCVI | 392 |
CCVII | 395 |
CCVIII | 399 |
CCIX | 400 |
CCX | 401 |
CCXII | 405 |
CCXIV | 406 |
CCXVII | 407 |
CCXVIII | 409 |
CCXIX | 411 |
CCXX | 413 |
CCXXII | 414 |
CCXXIII | 416 |
CCXXV | 417 |
CCXXVI | 419 |
CCXXVII | 421 |
CCXXIX | 423 |
CCXXXI | 424 |
CCXXXIV | 425 |
CCXXXV | 427 |
CCXXXVI | 428 |
CCXXXVII | 429 |
CCXXXVIII | 430 |
CCXXXIX | 435 |
CCXL | 436 |
CCXLI | 437 |
CCXLIII | 438 |
CCXLIV | 440 |
CCXLV | 441 |
CCXLVI | 443 |
CCXLVII | 446 |
CCXLVIII | 447 |
CCXLIX | 448 |
CCLII | 453 |
CCLIV | 454 |
CCLV | 456 |
CCLVI | 458 |
CCLIX | 459 |
CCLX | 461 |
CCLXI | 464 |
CCLXII | 469 |
CCLXIII | 472 |
CCLXIV | 473 |
CCLXVI | 476 |
CCLXVIII | 478 |
CCLXIX | 481 |
CCLXX | 485 |
CCLXXI | 487 |
CCLXXIII | 489 |
CCLXXV | 491 |
CCLXXVII | 496 |
CCLXXVIII | 497 |
CCLXXIX | 509 |
CCLXXX | 510 |
CCLXXXI | 511 |
CCLXXXII | 512 |
CCLXXXIV | 515 |
CCLXXXV | 516 |
CCLXXXVI | 517 |
CCLXXXVIII | 519 |
CCXC | 520 |
CCXCIII | 523 |
CCXCIV | 524 |
CCXCV | 525 |
CCXCVI | 526 |
CCXCVII | 527 |
CCXCVIII | 530 |
CCCI | 531 |
CCCII | 534 |
CCCIII | 535 |
CCCIV | 536 |
CCCV | 537 |
CCCVII | 538 |
CCCVIII | 540 |
CCCX | 543 |
CCCXI | 544 |
CCCXII | 545 |
CCCXIII | 546 |
CCCXIV | 555 |
CCCXV | 556 |
CCCXVI | 557 |
CCCXVII | 561 |
CCCXVIII | 562 |
CCCXIX | 564 |
CCCXX | 567 |
CCCXXI | 571 |
CCCXXII | 573 |
CCCXXIV | 576 |
CCCXXV | 580 |
CCCXXVI | 583 |
CCCXXVII | 584 |
CCCXXIX | 590 |
CCCXXX | 593 |
CCCXXXI | 595 |
CCCXXXIII | 602 |
CCCXXXIV | 605 |
CCCXXXV | 606 |
CCCXXXVI | 609 |
CCCXXXVII | 616 |
CCCXXXVIII | 618 |
CCCXXXIX | 619 |
623 | |
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Conjugated Polymers: The Novel Science and Technology of Highly Conducting ... J.L. Brédas,R. Silbey No preview available - 2012 |
Common terms and phrases
A.J. Heeger absorption spectrum alkyl backbone band bipolarons bond calculated charge carriers Chem chemical concentration conducting polymers conformation conjugated polymers conjugation length counterions density disorder dopant doping doping level draw ratio effect electrical conductivity electronic structure energy equation excitation experimental Fermi energy fibers fibrils frequency function Heeger increase infrared insulator intensity interaction Kajzar layer LB films Lett MacDiarmid Macromolecules materials measured metallic modes molecular weight molecules monolayer monomer monomer units multilayer Nonlinear Optical observed obtained oligomers oriented P3ATs P3OT parameters photon Phys polaron polaron lattice polyacetylene polyaniline polyene polymer chains polymerization polypyrrole polythiophene potential properties pyrrole Raman spectra room temperature S/cm samples scattering shown in figure shows side groups solid soliton soluble solution solvent spectroscopy spectrum statistical length stretching studies substrate surface Synth synthesis temperature dependence thermochromism thickness thin films thiophene transition undoped vibrational voltage Zerbi