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Page 237
... DETERMINATION OF ION CONCENTRATION Extensive effort has gone into the development of accurate and conve- nient methods for the measurement of pH ... DETERMINATION OF ION CONCENTRATION 237 7-7 Potentiometric Determination of Ion Concentration.
... DETERMINATION OF ION CONCENTRATION Extensive effort has gone into the development of accurate and conve- nient methods for the measurement of pH ... DETERMINATION OF ION CONCENTRATION 237 7-7 Potentiometric Determination of Ion Concentration.
Page 349
... determining step - equal to the rate constant of that step times the equilibrium concentrations of the species entering into it , or k2 [ C12H23O + ] [ H2O ] . The concentration of the intermediate cannot be experimentally determined ...
... determining step - equal to the rate constant of that step times the equilibrium concentrations of the species entering into it , or k2 [ C12H23O + ] [ H2O ] . The concentration of the intermediate cannot be experimentally determined ...
Page 372
... determining step , in which a proton is removed from the reaction intermediate by a base : HGH ++ A- k2 , GH + HA ( 10 ... determined by the equilib- rium constant K = = k_1 [ HGH + ] [ A- ] [ HG ] [ HA ] ( 10-139 ) Combining these two ...
... determining step , in which a proton is removed from the reaction intermediate by a base : HGH ++ A- k2 , GH + HA ( 10 ... determined by the equilib- rium constant K = = k_1 [ HGH + ] [ A- ] [ HG ] [ HA ] ( 10-139 ) Combining these two ...
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Common terms and phrases
absorption acid adsorbed adsorption amino amount behavior benzene Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride cm³ coefficient complex components concentration containing corresponding curve described diagram dipole dissociation distance effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example force free energy frequency function H₂O heat hydrogen atom hydrogen bonds increase interaction ionic ionization k₁ k₂ kcal kcal/mol kinetic magnetic field magnitude material measured membrane mixture molar mole fraction molecular weight molecules nuclei occurs orbital osmotic pressure oxidation oxygen particles polar potential protein proton quantum number radiation rate constant ratio reactant reaction represented resonance rotation sample shown in Figure sodium solid solubility solvent species spectrum spin structure substance sucrose surface tension temperature tion titration torr transition triplet tube vapor pressure velocity vibrational viscosity volume wavelength zero