Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications ... |
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Page 129
... energy of the system itself during a change at constant temperature and pressure is equal to the maximum work that can be done by the system in the course of the change less the pressure - volume work that must be done against the ...
... energy of the system itself during a change at constant temperature and pressure is equal to the maximum work that can be done by the system in the course of the change less the pressure - volume work that must be done against the ...
Page 131
... energy . The most convenient of the three can be chosen for use in a particular problem . FREE ENERGY CHANGES FOR CHEMICAL REACTIONS A very significant application of the free energy function is in the evaluation of the driving force ...
... energy . The most convenient of the three can be chosen for use in a particular problem . FREE ENERGY CHANGES FOR CHEMICAL REACTIONS A very significant application of the free energy function is in the evaluation of the driving force ...
Page 132
... energy change for the reaction . Solution : The enthalpy change is found by subtracting twice the enthalpy of forma- tion of glycine from the sum of the enthalpies of formation of glycylglycine and of water : AH ° = - - 178.12 . 68.32 2 ...
... energy change for the reaction . Solution : The enthalpy change is found by subtracting twice the enthalpy of forma- tion of glycine from the sum of the enthalpies of formation of glycylglycine and of water : AH ° = - - 178.12 . 68.32 2 ...
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absorption acid adsorbed adsorption amino amount behavior benzene Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride cm³ coefficient complex components concentration containing corresponding curve described diagram dipole dissociation distance effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example force free energy frequency function H₂O heat hydrogen atom hydrogen bonds increase interaction ionic ionization k₁ k₂ kcal kcal/mol kinetic magnetic field magnitude material measured membrane mixture molar mole fraction molecular weight molecules nuclei occurs orbital osmotic pressure oxidation oxygen particles polar potential protein proton quantum number radiation rate constant ratio reactant reaction represented resonance rotation sample shown in Figure sodium solid solubility solvent species spectrum spin structure substance sucrose surface tension temperature tion titration torr transition triplet tube vapor pressure velocity vibrational viscosity volume wavelength zero