Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications ... |
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Page 96
... equal to zero . From the first law , it then follows that - q = - W ( 3-12 ) This is equivalent to the statement that any heat absorbed is converted into the work required when the gas expands against its surroundings . Furthermore ...
... equal to zero . From the first law , it then follows that - q = - W ( 3-12 ) This is equivalent to the statement that any heat absorbed is converted into the work required when the gas expands against its surroundings . Furthermore ...
Page 129
... equal to the maximum work that can be done by the system in the course of the change less the pressure - volume work ... equal to qsurroundings / T , which is equal to -9system / T , which in turn is equal to -AH AHsystem / T . Therefore ...
... equal to the maximum work that can be done by the system in the course of the change less the pressure - volume work ... equal to qsurroundings / T , which is equal to -9system / T , which in turn is equal to -AH AHsystem / T . Therefore ...
Page 198
... equal to K1 , and K , is approximately equal to K2 , and the only intermediate present then is AH , - . It is when the acidities of protons x and y approach one another that things become more complicated . In the limit of equal acid ...
... equal to K1 , and K , is approximately equal to K2 , and the only intermediate present then is AH , - . It is when the acidities of protons x and y approach one another that things become more complicated . In the limit of equal acid ...
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absorption acid adsorbed adsorption amino amount behavior benzene Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride cm³ coefficient complex components concentration containing corresponding curve described diagram dipole dissociation distance effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example force free energy frequency function H₂O heat hydrogen atom hydrogen bonds increase interaction ionic ionization k₁ k₂ kcal kcal/mol kinetic magnetic field magnitude material measured membrane mixture molar mole fraction molecular weight molecules nuclei occurs orbital osmotic pressure oxidation oxygen particles polar potential protein proton quantum number radiation rate constant ratio reactant reaction represented resonance rotation sample shown in Figure sodium solid solubility solvent species spectrum spin structure substance sucrose surface tension temperature tion titration torr transition triplet tube vapor pressure velocity vibrational viscosity volume wavelength zero