Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications ... |
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Page 349
To explain the observed kinetic equation , one may assume that the process
given by Equation ( 10-34 ) , with a rate constant ką , is the slowest of all the steps
indicated , constituting for the reaction a bottleneck or rate - determining step .
To explain the observed kinetic equation , one may assume that the process
given by Equation ( 10-34 ) , with a rate constant ką , is the slowest of all the steps
indicated , constituting for the reaction a bottleneck or rate - determining step .
Page 353
mine molecules into bromine atoms : Br , k ,, 2Br . Step 1 ( 10-51 ) A bromine
atom then reacts with a hydrogen molecule : Br : + H , k2 , HBr + H. Step 2 ( 10-52
) The hydrogen atom produced here can react with another bromine molecule : H
. + ...
mine molecules into bromine atoms : Br , k ,, 2Br . Step 1 ( 10-51 ) A bromine
atom then reacts with a hydrogen molecule : Br : + H , k2 , HBr + H. Step 2 ( 10-52
) The hydrogen atom produced here can react with another bromine molecule : H
. + ...
Page 355
We choose step 3 to express the rate : d [ C , H , ] d [ C2H6 ] k3 ( C2H ,: ] ( 10-72 )
dt dt The hydrogen atom and the ethyl radical are each treated as a reactive
intermediate : + - d [ H . ] k [ C , H , :) – k , [ H ] [ C , H . ] – ky [ H. ] C , H ,: ] = ( 10-73
) ...
We choose step 3 to express the rate : d [ C , H , ] d [ C2H6 ] k3 ( C2H ,: ] ( 10-72 )
dt dt The hydrogen atom and the ethyl radical are each treated as a reactive
intermediate : + - d [ H . ] k [ C , H , :) – k , [ H ] [ C , H . ] – ky [ H. ] C , H ,: ] = ( 10-73
) ...
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Contents
1STATES OF MATTER | 1 |
2SOLUTIONS | 51 |
SECOND LAW AND EQUILIBRIUM | 115 |
Copyright | |
7 other sections not shown
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Common terms and phrases
absorption acid activity adsorbed amount applied atom base bond Calculate carbon carbon tetrachloride cell Chapter charge Chem chemical complex components concentration constant containing corresponding depends described determined direction distance effect electric electron energy enthalpy entropy enzyme equal equation equilibrium example expression field Figure force fraction free energy frequency function given glucose heat hydrogen increase indicated involved ionization kinetic light liquid magnetic material measured membrane method mixture mole molecular molecules motion nucleus observed obtained occurs orbital organic oxygen particles phase positive possible potential present pressure properties protein radiation reactant reaction region represented sample shown shows sodium solid solution solvent species spectrum step structure surface surface tension temperature tion transition unit usually vapor pressure various vibrational volume wave
Bibliographic information
| Title | Physical Chemistry and Its Biological Applications |
| Author | Wallace S. Brey |
| Edition | illustrated |
| Publisher | Academic Press, 1978 |
| Original from | the University of California |
| Digitized | 20 Apr 2007 |
| ISBN | 0121331504, 9780121331504 |
| Length | 589 pages |
| Export Citation | BiBTeX EndNote RefMan |