Advances in Physical Organic Chemistry APL

acid AGST alcohol alkyl amine anionic aqueous aromatic carbenes atoms base bimolecular binding Bunton calculated carbene catalysis cationic micelles Chem chemical Chemistry compounds concentration counterions CTABr cyclisation cyclisation reactions cycloalkanes cyclohexane cyclopropane electron EM-values EM's end-groups energy entropy equilibrium constant ether experimental Fendler formation functional micelles Galli H₂O head groups Hibbert hydrogen bond hydrolysis hydrophilic hydrophobic hydroxide ion Illuminati interactions intermediate intramolecular intramolecular hydrogen bond ionic irradiation isotope effect k₁ k₂ kcal kinetic Mandolini Me₂SO mechanism methylene micellar effects micellar pseudophase micellar surface micelles microemulsions mol¹ molecular molecule monoanions Moss nucleophilic observed orbital oxygen p-nitrophenyl Phys proton removal proton transfer proton-transfer rate coefficients rate constants reactants reactivity ring closure ring-size Romsted Scheme second-order rate constants similar singlet singlet carbene solution solvent Stern layer structure substituents substrate surfactant Table tautomers temperature tion transition triplet carbene vesicles Winnik