## Molecular Basis of Polymer Networks: Proceedings of the 5th IFF-ILL Workshop, Jülich, Fed. Rep. of Germany, October 5–7, 1988The workshop on the "Molecular Basis of Polymer Networks", held October 5- 7, 1988 in 1iilich, FRG, continued a series of workshops jointly organized by the Institute Laue Langevin (ILL) in Grenoble, and the Institute of Solid State Physics of the KFA, 1iilich. The aim of this workshop was to provide a platform for discussions between theoreticians and experimentalists interested in the physics of polymer networks, in the hope that the two types of discussion would be synergistic. As revealed by the title of this workshop, the main focus of the lectures was on molecular aspects of the problem. The individual parts of these proceedings cover various approaches. Following quite general comments from a physicist examining the situation from "outside", various new theoretical concepts are developed. During the last decade the advent of Small Angle Neutron Scattering (SANS) has allowed the molecular structure of polymer networks to be studied and thus the reliability of the theories to be tested directly at the molecular level. Recent advances in this field are presented. The use of new techniques such as 2H NMR or QELS and the refinements of more classical, mechanical experimental measure ments have provided new information about the relation between the macroscopic behavior and the microscopic structure of polymer networks. Some recent results in this area are discussed for both chemically cross-linked networks and gels built by specific interchain interactions. |

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Page 133

This factor , which varies as q1 / 4 , might be expected to alter the

the swollen network , and hence the elastic moduli . The aim of this study is to

examine the role of the individual network chains in the

and ...

This factor , which varies as q1 / 4 , might be expected to alter the

**free energy**ofthe swollen network , and hence the elastic moduli . The aim of this study is to

examine the role of the individual network chains in the

**free energy**of the gel ,and ...

Page 135

The elastic

the end - points of this superchain , Rs , is ... where chain unfolding is absent

since Rs and RG follow the same concentration dependence , the excess

The elastic

**free energy**associated with the separation of the distance betweenthe end - points of this superchain , Rs , is ... where chain unfolding is absent

since Rs and RG follow the same concentration dependence , the excess

**free****energy**...Page 173

For Gaussian chains a harmonic trial potential UngosRʻ ( s ) leads to a

the variational parameter determines qo . In the case of flexible chains 4o turns

out to ...

For Gaussian chains a harmonic trial potential UngosRʻ ( s ) leads to a

**free****energy**of the form F = F ( M , 1 , 90 ) . Minimizing the**free energy**with respect tothe variational parameter determines qo . In the case of flexible chains 4o turns

out to ...

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### Contents

Remarks | 2 |

By S F Edwards With 1 Figure | 17 |

FluctuationInduced Deformation Dependence of the FloryHuggins | 35 |

Copyright | |

14 other sections not shown

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Molecular Basis of Polymer Networks: Proceedings of the 5th IFF-ILL Workshop ... Artur Baumgärtner,Claude E. Picot No preview available - 2011 |

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