Advances in High Temperature Chemistry, Volume 1
Elsevier, Oct 22, 2013 - Science - 346 pages
Advances in High Temperature Chemistry, Volume 1 describes the complexities and special and changing characteristics of high temperature chemistry.
After providing a brief definition of high temperature chemistry, this nine-chapter book goes on describing the experiments and calculations of diatomic transition metal molecules, as well as the advances in applied wave mechanics that may contribute to an understanding of the bonding, structure, and spectra of the molecules of high temperature interest. The next chapter provides a summary of gaseous ternary compounds of the alkali metals used in high temperature chemistry. This topic is followed by discussions on the thermochemical properties of some simple solids in terms of valence states of the metallic elements and of the electrons in metals, on anions, and in aqueous solutions. Other chapters are concerned with the stepwise bond dissociation energies in a number of polyvalent metal fluorides and the unique possibilities for chemical syntheses, which are available through high temperature species. The final chapters are devoted to the techniques, temperature ranges, and accuracy of high temperature calorimetry. These chapters also include surveys on the nature of thermal plasmas for high temperature chemistry.
This book is of benefit to high temperature chemists and specialized engineers.
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Chapter 3 Electronic Structure of Molecules of High Temperature Interest
Chapter 4 Gaseous Ternary Compounds of the Alkali Metals
Chapter 5 Valence States in High Temperature Chemistry Energetic Structures inTransitional Elements
Chapter 6 Bond Energy Relationships in Polyvalent Metal Fluorides
Chapter 7 The Chemical Reactions of High Temperature Species
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acetylene adiabatic alkali approximation argon Arkiv Fysik atoms Barrow basis functions Berkowitz bond dissociation energies Büchler calorimeter calorimetry carbon cathode Chem chemical Clementi cold plasmas composition compounds configuration configuration interaction correlation energy diatomic molecules dimer discussed Drowart electronic structure elements enthalpy entropy equations equilibrium excited experimental flame fluorides furnace gaseous gases given in Table Goldfinger ground halides Hartree–Fock calculations heat transfer heats of atomization high temperature chemistry Hildenbrand hydrogen hydroxide induction plasma ionic ionization ions J. L. Margrave kcal kcal/mole Khim Kusch Lagerqvist linear lithium mass spectrometric matrix Hartree–Fock measured melting method mixed species mole molecular Nesbet Novikov nozzle observed obtained operation orbital oxides oxygen partial pressures Phys plasma torch Porter Proc produced quenching reaction Schoonmaker Slater determinant sodium solid spectra spectroscopic studied symmetry thermal plasmas thermodynamic tion Torr transition metal tube valence values voltage wavefunctions ZrF4