Polymer Interface and AdhesionPoly mer Interface and Adhesion provides the critical basis for further advancement in thisfield. Combining the principles of interfacial science, rheology, stress analysis, and fracturemechanics, the book teaches a new approach to the analysis of long standing problemssuch as: how is the interface formed; what are its physical and mechanical properties;and how does the interface modify the stress field and fracture strength of the material.The book offers many outstanding features, including extensive listings of pertinent references, exhaustive tabulations of the interfacial properties of polymers, critical reviews ofthe many conflicting theories, and complete discussions of coupling agents, adhesion promotion, and surface modifications. Emphasis is placed on physical concepts and mechanisms, using clear, understandable mathematics.Polymer Interface and Adhesion promotes a more thorough understanding of the physical, mechanical, and adhesive properties of multiphase, polymer systems. Polymer scientistsand engineers, surface chemists, materials scientists, rheologists, as well as chemical andmechanical engineers interested in the research, development or industrial applications ofpolymers, plastics, fibers, coatings, adhesives, and composites need this important newsource b |
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Page vi
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Page ix
... Theories of van der Waals Forces 2.2 Additivity and Fractional Contributions of Various 30 Types of Molecular Forces 40 2.3 Approximations for Unlike ... Theory 54 References 62 3 . INTERFACIAL AND SURFACE TENSIONS OF POLYMER MELTS AND ix.
... Theories of van der Waals Forces 2.2 Additivity and Fractional Contributions of Various 30 Types of Molecular Forces 40 2.3 Approximations for Unlike ... Theory 54 References 62 3 . INTERFACIAL AND SURFACE TENSIONS OF POLYMER MELTS AND ix.
Page xii
... Theory References 460 456 13 . EFFECT OF INTERNAL STRESS ON BOND STRENGTH 465 467 13.1 Shrinkage of a Coating ... Theory 486 Part I. Fundamentals of Fracture Mechanics 14.1 Linear Elastic Fracture Mechanics 14.2 Local Plastic Flow 484 ...
... Theory References 460 456 13 . EFFECT OF INTERNAL STRESS ON BOND STRENGTH 465 467 13.1 Shrinkage of a Coating ... Theory 486 Part I. Fundamentals of Fracture Mechanics 14.1 Linear Elastic Fracture Mechanics 14.2 Local Plastic Flow 484 ...
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Contents
INTERFACIAL THERMODYNAMICS | 1 |
MOLECULAR INTERPRETATIONS | 29 |
INTERFACIAL AND SURFACE TENSIONS | 67 |
CONTACT ANGLES OF LIQUIDS ON SOLID POLYMERS | 133 |
SURFACE TENSION AND POLARITY OF SOLID POLYMERS | 169 |
WETTING OF HIGHENERGY SURFACES | 215 |
DYNAMIC CONTACT ANGLES AND WETTING KINETICS | 235 |
EXPERIMENTAL METHODS FOR CONTACT ANGLES | 257 |
FORMATION OF ADHESIVE BOND | 359 |
WEAK BOUNDARY LAYERS | 449 |
EFFECT OF INTERNAL STRESS ON BOND STRENGTH | 465 |
FRACTURE OF ADHESIVE BOND | 475 |
Analysis and Testing of Adhesive Bonds | 497 |
CREEP FATIGUE AND ENVIRONMENTAL EFFECTS | 571 |
Calculation of Surface Tension and Its Nonpolar | 613 |
BASIC CONCEPT AND LOCUS OF FAILURE | 337 |
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Common terms and phrases
acid adherend Adhes adhesive bond adhesive fracture adhesive joint adhesive layer adhesive thickness adsorption aluminum Appl bond strength bondability bulk butt joint Chem chemical bonding coefficient cohesive Colloid Colloid Interface Sci constant contact angle copolymer crack critical surface tension cross-linked curve density diffusion dipole drop dyne/cm Effect epoxy equation equilibrium experimental film fracture energy given glass groups harmonic-mean high-energy surfaces increases interfacial failure interfacial tension joint strength L. H. Lee lap joints low-energy metal method mode molecular weight molecules obtained oxide peel force peel strength phase Phys plasma plastic plate plot polar poly poly(ethylene terephthalate poly(methyl methacrylate Poly(vinyl chloride Polydimethylsiloxane polyethylene polyisobutylene Polym polymer surfaces polypropylene polystyrene polytetrafluoroethylene rubber Schonhorn shear strength shear stress silane solid specimen surface tension Table temperature tensile testing liquids theory values versus viscoelastic W. A. Zisman weak boundary layer wettability wetting York zero