Advanced Organic Chemistry: Reactions and synthesis

acylation adduct alcohols aldehydes aldol condensations alkenes ALKYLATION OF NUCLEOPHILIC allylic amides amines anion anti boron bromide C-alkylation C. H. Heathcock C₂H carbanions CARBON NUCLEOPHILES carbon-carbon carbonyl compounds CARBONYL GROUPS carboxylic acids catalyst cation CH,O CH₂ CH3 CH CHAPTER 1 ALKYLATION CHAPTER 2 REACTIONS Chem chloride CO,CH CO₂C₂H CO₂H conjugate addition cyclic cycloaddition reactions cyclohexanone deprotonation Diels-Alder dienophile DMSO double bond E. J. Corey ENAMINES enantioselective ENOLATES AND ENAMINES entry esters examples formation FUNCTIONAL GROUPS give H CH H H H H,C CH H,C H,C H. C. Brown H. O. House H₂C H₂O halogen hydride hydrogen imine intermediate intramolecular ketones lithium mechanism metal methyl molecules NUCLEOPHILES WITH CARBONYL NUCLEOPHILIC CARBON NUCLEOPHILIC SUBSTITUTION oxygen proton react reaction conditions REACTIONS OF CARBON reactive reagents regioselectivity Scheme SECTION silyl enol ether sodium solvents stereochemistry stereoselectivity steric structure Synth synthesis synthetic Tetrahedron Lett transition ylides