Colloidal and Morphological Behavior of Block and Graft Copolymers: Proceedings of an American Chemical Society Symposium Held at Chicago, Illinois, September 13–18, 1970Gunther E. Molau The molecules of block and graft copolymers are molecules of a higher order; they consist of homopolymer subchains which are interconnected by chemical valence bonds. This structural com plexity is manifested in the unusual behavior of block and graft copolymers both in solution and in bulk. Many types of interac tions are possible in block and graft copolymers in the solid state. Polymer subchains of one molecule can interact with other polymer subchains which may belong to the same molecule or to different molecules. Since polymer chains of chemically different composition are usually incompatible, thermodynamically unfavorable as well as thermodynamically favorable interactions exist in the solid state. In solutions of block and graft copolymers, the sit uation becomes even more complex, because interactions between the solvent molecules and the various subchains of the copolymer mole cules occur in addition to the interactions between the polymer chains. This multitude of interactions gives rise to a wide spec trum of colloidal and morphological properties which have no paral lel in less complex polymer systems such as homopolymers or random copolymers. Research on the colloidal and morphological behavior of block and graft copolymers is a relatively new field of endeavor. It started in 1954, when F. M. Merrett fractionated mixtures of grafted na tural rubber with the corresponding homopolymers and observed that colloidal sols were formed at certain points during his fractional precipitations. |
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Page 273
... versus which in turn may be compared with the Cm versus M - 2 / 3 relations for the ternary systems such as shown in Figure 2 . It is seen from Figure 2 that in a group of solvents such as CHL ( 850 ) , THF , TOL , and MEK , the Em is ...
... versus which in turn may be compared with the Cm versus M - 2 / 3 relations for the ternary systems such as shown in Figure 2 . It is seen from Figure 2 that in a group of solvents such as CHL ( 850 ) , THF , TOL , and MEK , the Em is ...
Page 274
... versus My data of the DEM solutions did not show any anomalies at all , or at least , those detectable by the [ n ] measurements . In this solvent , DEM , the conformational change takes palce at the central PST subchains , whereas the ...
... versus My data of the DEM solutions did not show any anomalies at all , or at least , those detectable by the [ n ] measurements . In this solvent , DEM , the conformational change takes palce at the central PST subchains , whereas the ...
Page 297
... versus strain in Figure 2. The ex- perimental curve of true stress versus strain shown in Figure 2 displays a smooth transition between two analytical functions : 0 kg 2 cm = E , ( t ) = 510 ( 1 ) 3 19 kg 2 E ( t ) 31 m = cm 1 ...
... versus strain in Figure 2. The ex- perimental curve of true stress versus strain shown in Figure 2 displays a smooth transition between two analytical functions : 0 kg 2 cm = E , ( t ) = 510 ( 1 ) 3 19 kg 2 E ( t ) 31 m = cm 1 ...
Contents
MicromorphologyProperty Relationships in Graft | 1 |
The Effect of Environment on the Morphology of Styrene | 21 |
Light Scattering from TwoPhase Polymer System having | 33 |
Copyright | |
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Colloidal and Morphological Behavior of Block and Graft Copolymers ... Gunther Molau Limited preview - 2012 |
Colloidal and Morphological Behavior of Block and Graft Copolymers ... Gunther Molau No preview available - 1971 |
Colloidal and Morphological Behavior of Block and Graft Copolymers ... Gunther Molau No preview available - 2012 |
Common terms and phrases
acid copolymer acrylic acid adsorbed adsorption behavior benzene Benzene Cast block and graft block copolymer block samples Chem coils colloidal component composition concentration containing crosslinks crystallites curve cyclohexane density dimethylsiloxane blocks diphenylsiloxane blocks dispersed elastomers electron micrographs emulsions equation Figure fraction gels graft copolymers homopolymer impact strength increase interactions intrinsic viscosity ionomer ionomer blends isotherms Kraton lipid matrix melt flow membrane microphase separation mixture MMA homopolymer modulus molecular weight molecules morphology observed ORIENTATION FUNCTION p-XY peroxide phase separation plastic plot PMMA PMMA-PST-PMMA PMST polar poly polybutadiene polydimethylsiloxane polyethylene Polymer Sci polymerization polystyrene polystyrene block Potassium Acrylate properties proteins random copolymers ratio reaction region S/MMA block segments shown shows silver oxide solubility parameter solution solvent specimens spherical domains strain styrene subchains surface Table temperature tensile Thermolastic 125 toluene triblock copolymers ultrathin sections values versus