Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 362
... chromophore which commonly occurs in proteins is the disulfide group . This group can exist in either of two skewed conformations of opposite chirality because of the restricted rotation about the SS bond . Inherently disymmetric ...
... chromophore which commonly occurs in proteins is the disulfide group . This group can exist in either of two skewed conformations of opposite chirality because of the restricted rotation about the SS bond . Inherently disymmetric ...
Page 489
... chromophore is inherently op- tically active and ( 2 ) when a chromophore is optically active by virtue of the perturbing effects of a static asymmetric environment . In order for the first case to obtain , the transition itself and the ...
... chromophore is inherently op- tically active and ( 2 ) when a chromophore is optically active by virtue of the perturbing effects of a static asymmetric environment . In order for the first case to obtain , the transition itself and the ...
Page 491
... chromophore belongs ; Schellman also demon- strated that the higher the symmetry of the chromophore , the higher the multipole ( i.e. , monopole , dipole ) term in V needed to induce optical activity . Both of these findings suggest ...
... chromophore belongs ; Schellman also demon- strated that the higher the symmetry of the chromophore , the higher the multipole ( i.e. , monopole , dipole ) term in V needed to induce optical activity . Both of these findings suggest ...
Contents
Direct Volume Change | 22 |
Density | 32 |
Derivation of the Partial Specific Volume from | 62 |
Copyright | |
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a-helix absorption acid Acta angle axial ratio B-structure Biochem Biochemistry Biol buffer c₂ calculated CD spectra Chem chromophore circular dichroism coefficient conformation constant Cotton effects cross-section curves denaturation determined dialyzate diffusible components dilute electron density ellipsoids ellipticity enzyme equation equilibrium exciton factor function gm/ml grams Guinier helical helix hemocyanin hemoglobin intensity interaction investigated Kratky lysozyme macromolecule magnetic measurements membrane method mg/ml molal molecular weight molecule myoglobin negative nondiffusible obtained optical activity osmometers osmotic pressure parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides Porod primary beam procedure protein component protein solution radii radius of gyration residues rotational strength sample Schellman Section shape small-angle scattering small-angle X-ray scattering solvent solvent medium spectrum structure studies subsidiary maxima subunits T₁ temperature theoretical scattering curves Tinoco tion transition v₂ wavelength zero