Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 380
... equation . How- ever , as seen in Fig . 4 , the ORD curve of purely helical forms cannot be represented by a one - term Drude equation . The shapes of the curves suggest that they may be approximated by the following type of equation ...
... equation . How- ever , as seen in Fig . 4 , the ORD curve of purely helical forms cannot be represented by a one - term Drude equation . The shapes of the curves suggest that they may be approximated by the following type of equation ...
Page 381
... equation used in the A , method with A , A , and k = Zaidi2 . do Σιαλ ; ” . Since we consider only the first term of the expansion , the restriction that the rotation be very far from any absorption bands must be obeyed if the one ...
... equation used in the A , method with A , A , and k = Zaidi2 . do Σιαλ ; ” . Since we consider only the first term of the expansion , the restriction that the rotation be very far from any absorption bands must be obeyed if the one ...
Page 389
... equation one is able to cancel these effects to some extent by combining the use of a ' , and b'o values . 2. The Moffitt Equation and the Two - Term Drude Equation So far we have suggested two equations for analyzing the ORD curves of ...
... equation one is able to cancel these effects to some extent by combining the use of a ' , and b'o values . 2. The Moffitt Equation and the Two - Term Drude Equation So far we have suggested two equations for analyzing the ORD curves of ...
Contents
Direct Volume Change | 22 |
Density | 32 |
Derivation of the Partial Specific Volume from | 62 |
Copyright | |
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a-helix absorption acid Acta angle axial ratio B-structure Biochem Biochemistry Biol buffer c₂ calculated CD spectra Chem chromophore circular dichroism coefficient conformation constant Cotton effects cross-section curves denaturation determined dialyzate diffusible components dilute electron density ellipsoids ellipticity enzyme equation equilibrium exciton factor function gm/ml grams Guinier helical helix hemocyanin hemoglobin intensity interaction investigated Kratky lysozyme macromolecule magnetic measurements membrane method mg/ml molal molecular weight molecule myoglobin negative nondiffusible obtained optical activity osmometers osmotic pressure parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides Porod primary beam procedure protein component protein solution radii radius of gyration residues rotational strength sample Schellman Section shape small-angle scattering small-angle X-ray scattering solvent solvent medium spectrum structure studies subsidiary maxima subunits T₁ temperature theoretical scattering curves Tinoco tion transition v₂ wavelength zero