Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 495
... exciton coefficients in Eq . ( 49 ) or ( 50 ) must be determined . For our dimer here the coefficients are as follows [ Tinoco , 1963 ; see also Eq . ( 36 ) ] : C11 = + 1 / √2 ( Ciak ; i = 1 ; K = 1 ) ; C2 = + 1 / √2 ; C12 = C11 C21 ...
... exciton coefficients in Eq . ( 49 ) or ( 50 ) must be determined . For our dimer here the coefficients are as follows [ Tinoco , 1963 ; see also Eq . ( 36 ) ] : C11 = + 1 / √2 ( Ciak ; i = 1 ; K = 1 ) ; C2 = + 1 / √2 ; C12 = C11 C21 ...
Page 508
... exciton bands which give a net rotational strength of -5.23 DBM at an average wavelength of 186 mμ . The rotational strength here , then , is essentially the negative , short - wave- length branch ( R ) of the non - Gaussian CD envelope ...
... exciton bands which give a net rotational strength of -5.23 DBM at an average wavelength of 186 mμ . The rotational strength here , then , is essentially the negative , short - wave- length branch ( R ) of the non - Gaussian CD envelope ...
Page 519
... exciton contribution over the - exciton system ( see footnote 24 ) Zubkov and Vol'kenshtein specifically did . It was found that the ampli- tudes of the exciton bands are greatly enhanced by nonexciton contribu- tions and , in addition ...
... exciton contribution over the - exciton system ( see footnote 24 ) Zubkov and Vol'kenshtein specifically did . It was found that the ampli- tudes of the exciton bands are greatly enhanced by nonexciton contribu- tions and , in addition ...
Contents
Direct Volume Change | 22 |
Density | 32 |
Derivation of the Partial Specific Volume from | 62 |
Copyright | |
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a-helix absorption acid Acta angle axial ratio B-structure Biochem Biochemistry Biol buffer c₂ calculated CD spectra Chem chromophore circular dichroism coefficient conformation constant Cotton effects cross-section curves denaturation determined dialyzate diffusible components dilute electron density ellipsoids ellipticity enzyme equation equilibrium exciton factor function gm/ml grams Guinier helical helix hemocyanin hemoglobin intensity interaction investigated Kratky lysozyme macromolecule magnetic measurements membrane method mg/ml molal molecular weight molecule myoglobin negative nondiffusible obtained optical activity osmometers osmotic pressure parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides Porod primary beam procedure protein component protein solution radii radius of gyration residues rotational strength sample Schellman Section shape small-angle scattering small-angle X-ray scattering solvent solvent medium spectrum structure studies subsidiary maxima subunits T₁ temperature theoretical scattering curves Tinoco tion transition v₂ wavelength zero