Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 471
... THEORY OF OPTICAL ACTIVITY The earliest theories of optical activity were founded on classical no- tions concerning the interaction between electromagnetic radiation and matter . The names most notably associated with the development of ...
... THEORY OF OPTICAL ACTIVITY The earliest theories of optical activity were founded on classical no- tions concerning the interaction between electromagnetic radiation and matter . The names most notably associated with the development of ...
Page 472
... theory . The fundamental result of the Condon - Altar - Eyring ( CAE ) theory , or the so - called one - electron theory , can be loosely summarized as follows : here , optical activity is shown to arise in situations where an electron ...
... theory . The fundamental result of the Condon - Altar - Eyring ( CAE ) theory , or the so - called one - electron theory , can be loosely summarized as follows : here , optical activity is shown to arise in situations where an electron ...
Page 486
Sydney J. Leach. inherent difficulties associated with perturbation theory : perturbation theory per se is restricted to situations in which the perturbation energies are relatively small , whereas the matrix formalism is not ; moreover ...
Sydney J. Leach. inherent difficulties associated with perturbation theory : perturbation theory per se is restricted to situations in which the perturbation energies are relatively small , whereas the matrix formalism is not ; moreover ...
Contents
Direct Volume Change | 22 |
Density | 32 |
Derivation of the Partial Specific Volume from | 62 |
Copyright | |
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a-helix absorption acid Acta angle axial ratio B-structure Biochem Biochemistry Biol buffer c₂ calculated CD spectra Chem chromophore circular dichroism coefficient conformation constant Cotton effects cross-section curves denaturation determined dialyzate diffusible components dilute electron density ellipsoids ellipticity enzyme equation equilibrium exciton factor function gm/ml grams Guinier helical helix hemocyanin hemoglobin intensity interaction investigated Kratky lysozyme macromolecule magnetic measurements membrane method mg/ml molal molecular weight molecule myoglobin negative nondiffusible obtained optical activity osmometers osmotic pressure parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides Porod primary beam procedure protein component protein solution radii radius of gyration residues rotational strength sample Schellman Section shape small-angle scattering small-angle X-ray scattering solvent solvent medium spectrum structure studies subsidiary maxima subunits T₁ temperature theoretical scattering curves Tinoco tion transition v₂ wavelength zero