Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 428
... transition it is prefer- able to study the far - UV Cotton effects in more detail . The most thoroughly characterized conformational transition , both the- oretically and experimentally , is the helix - to - coil transition which occurs ...
... transition it is prefer- able to study the far - UV Cotton effects in more detail . The most thoroughly characterized conformational transition , both the- oretically and experimentally , is the helix - to - coil transition which occurs ...
Page 470
... transition . When the transition is electrically and magnetically allowed ( case I ) , the zero - order term dominates the expression for rotational strength and it is predicted that the correspond- ing absorption and CD bands of a ...
... transition . When the transition is electrically and magnetically allowed ( case I ) , the zero - order term dominates the expression for rotational strength and it is predicted that the correspond- ing absorption and CD bands of a ...
Page 501
... transition a of group 1 ) and the sition of the other amide ( transition b of group 2 ) . From Eq . appropriate expression for the rotational strength Ria of the n1 —— ̄ tran- sition here is21 ( 48a ) , the Ria = + V12Im [ μ2 m1 ] 2λ ...
... transition a of group 1 ) and the sition of the other amide ( transition b of group 2 ) . From Eq . appropriate expression for the rotational strength Ria of the n1 —— ̄ tran- sition here is21 ( 48a ) , the Ria = + V12Im [ μ2 m1 ] 2λ ...
Contents
Direct Volume Change | 22 |
Density | 32 |
Derivation of the Partial Specific Volume from | 62 |
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a-helix absorption acid Acta angle axial ratio B-structure Biochem Biochemistry Biol buffer c₂ calculated CD spectra Chem chromophore circular dichroism coefficient conformation constant Cotton effects cross-section curves denaturation determined dialyzate diffusible components dilute electron density ellipsoids ellipticity enzyme equation equilibrium exciton factor function gm/ml grams Guinier helical helix hemocyanin hemoglobin intensity interaction investigated Kratky lysozyme macromolecule magnetic measurements membrane method mg/ml molal molecular weight molecule myoglobin negative nondiffusible obtained optical activity osmometers osmotic pressure parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides Porod primary beam procedure protein component protein solution radii radius of gyration residues rotational strength sample Schellman Section shape small-angle scattering small-angle X-ray scattering solvent solvent medium spectrum structure studies subsidiary maxima subunits T₁ temperature theoretical scattering curves Tinoco tion transition v₂ wavelength zero