## Physical principles and techniques of protein chemistry, Volume 3 |

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Page 380

D. Moffitt

General Principles A simple ORD curve which is characteristic of a random-coil

conformation can be easily approximated by a one-term Drude

However ...

D. Moffitt

**Equation**for Proteins Containing a-Helix and Unordered Structures 1.General Principles A simple ORD curve which is characteristic of a random-coil

conformation can be easily approximated by a one-term Drude

**equation**.However ...

Page 389

In the Moffitt

combining the use of a'0 and b'0 values. 2. ...

of ...

In the Moffitt

**equation**one is able to cancel these effects to some extent bycombining the use of a'0 and b'0 values. 2. ...

**Equation**and the Two-Term Drude**Equation**So far we have suggested two**equations**for analyzing the ORD curvesof ...

Page 390

F. The Moffitt

existence of y3-structure was recognized a long time ago, the beauty of the a-

helical conformation proposed by Pauling and Corey drew attention away from

the ...

F. The Moffitt

**Equation**Applied to Proteins Containing /?-Structure Although theexistence of y3-structure was recognized a long time ago, the beauty of the a-

helical conformation proposed by Pauling and Corey drew attention away from

the ...

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a-helix absorption acid angle axial ratio Biol calculated CD spectra Chem chromophore circular dichroism coefficient Cohn complex conformation constant contribution corresponding Cotton effects creatine kinase denaturation determined dialyzate diffusible components dilute electron density enzyme equation equilibrated equilibrium exciton experimental frequency function gm/ml grams helical helix hemocyanin hemoglobin intensity interaction isomolal kinase Kratky macromolecule magnetic mass measurements membrane method milliliter mixture molal molecular weight molecule myoglobin negative nondiffusible number of moles observed obtained optical activity osmometers osmotic pressure paramagnetic parameter partial specific volume peptide Phys Pilz plot polymer polypeptides positive primary beam procedure protein component protein concentration protein solution pulse radius of gyration random coil residues rotational strength sample Scatchard Schellman Section shape small-angle scattering solvent solvent medium spectrum sphere structure studies subunits techniques temperature theoretical scattering curves tion transition volume change wavelength zero