Physical Principles and Techniques of Protein ChemistrySydney J. Leach Physical Principles and Techniques of Protein Chemistry Part C ... |
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Page 248
... paramagnetic entity . A paramagnetic species in solution has a profound effect on T1 of water protons and much of this chapter will be concerned with the use of paramagnetic probes though . some attention will be directed to the effects ...
... paramagnetic entity . A paramagnetic species in solution has a profound effect on T1 of water protons and much of this chapter will be concerned with the use of paramagnetic probes though . some attention will be directed to the effects ...
Page 265
... paramagnetic species may have a pro- found effect on the relaxation time of water protons . The paramagnetic contribution itself 1 / T1 , p [ see Eq . ( 1 ) ] , may be considered in two parts ; first , a direct effect on the protons in ...
... paramagnetic species may have a pro- found effect on the relaxation time of water protons . The paramagnetic contribution itself 1 / T1 , p [ see Eq . ( 1 ) ] , may be considered in two parts ; first , a direct effect on the protons in ...
Page 266
... paramagnetic spin flips between parallel and anti- parallel alignment with the applied magnetic field and creates ... paramagnetic contribution to the longitudinal relaxation of the protons within the first hydration sphere of a ...
... paramagnetic spin flips between parallel and anti- parallel alignment with the applied magnetic field and creates ... paramagnetic contribution to the longitudinal relaxation of the protons within the first hydration sphere of a ...
Contents
Direct Volume Change | 22 |
Density | 32 |
Derivation of the Partial Specific Volume from | 62 |
Copyright | |
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a-helix absorption acid Acta angle axial ratio B-structure band Biochem Biochemistry Biol buffer c₂ calculated CD spectra Chem chromophore circular dichroism coefficient complex conformation constant Cotton effects cross-section curves denaturation determined dialyzate diffusible components dilute electron density ellipsoids ellipticity enzyme equation equilibrium exciton factor function gm/ml grams Guinier helical helix hemocyanin hemoglobin intensity interaction investigated Kratky lysozyme macromolecule magnetic measurements membrane method mg/ml molal molecular weight molecule myoglobin negative nondiffusible obtained optical activity osmometers osmotic pressure parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides Porod primary beam procedure protein solution pulse radii radius of gyration residues rotational strength sample Schellman Section shape small-angle scattering small-angle X-ray scattering solvent solvent medium spectrum structure studies subsidiary maxima subunits T₁ temperature theoretical scattering curves Tinoco tion transition v₂ wavelength zero