Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
From inside the book
Results 6-10 of 83
Page 17
... defined as the fraction that the number of moles of any component represents of the total number of moles of all the components of the mixture. Such a concentration scale is very easily applied to gases, since the mole fraction is equal ...
... defined as the fraction that the number of moles of any component represents of the total number of moles of all the components of the mixture. Such a concentration scale is very easily applied to gases, since the mole fraction is equal ...
Page 24
... define these ratios as reduced variables: Pr : P/Pc, Tr I T/Tc, and Vr : V/Vc. In terms of reduced variables, Equation (1-28) then becomes 1 8T. Pr. +. W. (Vr. -. 5). : 3P. (129). If this equation is obeyed, two substances existing at the ...
... define these ratios as reduced variables: Pr : P/Pc, Tr I T/Tc, and Vr : V/Vc. In terms of reduced variables, Equation (1-28) then becomes 1 8T. Pr. +. W. (Vr. -. 5). : 3P. (129). If this equation is obeyed, two substances existing at the ...
Page 26
... defined as the product of the amount of charge separated and the dis— tance of separation. Since the charge on an electron is of the order of 10'10 electrostatic units (esu) and the distance between atoms is of the order of 10*8 cm, the ...
... defined as the product of the amount of charge separated and the dis— tance of separation. Since the charge on an electron is of the order of 10'10 electrostatic units (esu) and the distance between atoms is of the order of 10*8 cm, the ...
Page 27
... defined as the magnitude of the dipole produced by application of unit electric field to the molecule. The energy associated with either the ion—dipole or the ion—induced dipole force varies with the inverse fourth power of the distance ...
... defined as the magnitude of the dipole produced by application of unit electric field to the molecule. The energy associated with either the ion—dipole or the ion—induced dipole force varies with the inverse fourth power of the distance ...
Page 31
... defined character as a result of intermolecular hydrogen bonding: /O—CH2—CH3 H CH,—cn,—o'\ n The size of the aggregates, as well as the fraction of the total number of H \ Figure 1-13 Q Schematic arrangement of hydrogen bonds H ...
... defined character as a result of intermolecular hydrogen bonding: /O—CH2—CH3 H CH,—cn,—o'\ n The size of the aggregates, as well as the fraction of the total number of H \ Figure 1-13 Q Schematic arrangement of hydrogen bonds H ...
Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
Other editions - View all
Common terms and phrases
absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero