Interfacial Forces in Aqueous MediaThoroughly revised and reorganized, the second edition of Interfacial Forcesin Aqueous Media examines the role of polar interfacial and noncovalent interactions among biological and nonbiological macromolecules as well as biopolymers, particles, surfaces, cells, and both polar and apolar polymers. The book encompasses Lifshitz-van de |
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Results 6-10 of 95
Page 10
... equation qi is for the number of atoms per unit volume and β the constant in London's the interaction between two atoms i, and β = 3/4 α2hv (see eq. [II-4]): V ii = −β ii / 6 [II-6] where is the distance between the atoms i (see eq ...
... equation qi is for the number of atoms per unit volume and β the constant in London's the interaction between two atoms i, and β = 3/4 α2hv (see eq. [II-4]): V ii = −β ii / 6 [II-6] where is the distance between the atoms i (see eq ...
Page 13
... equations . Historical reviews are given by Mahanty and Ninham ( 1976 ) and by Nir ( 1976 ) . According to Lifshitz's theory ( 1955 ) ( see also Dzyaloshinskii et al . , 1961 ) , the approximate expression for the free energy of ...
... equations . Historical reviews are given by Mahanty and Ninham ( 1976 ) and by Nir ( 1976 ) . According to Lifshitz's theory ( 1955 ) ( see also Dzyaloshinskii et al . , 1961 ) , the approximate expression for the free energy of ...
Page 14
... Equation [ II - 26 ] can then be expressed as : Ai ( e ) = 3h √ ∞ 3 do 4 元 0 2j ε1 ( i ) -1 ε1 ( ion ) +1 · j ̃3 j = 1 [ II - 26A ] If the dielectric permeability of a material is known along the imaginary frequency axis , io , the ...
... Equation [ II - 26 ] can then be expressed as : Ai ( e ) = 3h √ ∞ 3 do 4 元 0 2j ε1 ( i ) -1 ε1 ( ion ) +1 · j ̃3 j = 1 [ II - 26A ] If the dielectric permeability of a material is known along the imaginary frequency axis , io , the ...
Page 16
... equation ( eq . [ II - 36 ] ) is not precisely the equation that was used by Dupré ( 1869 ) ; Dupré gave this equation in a slightly different form , containing an ( erroneous ) factor 2 before the Y12 term . However , following ...
... equation ( eq . [ II - 36 ] ) is not precisely the equation that was used by Dupré ( 1869 ) ; Dupré gave this equation in a slightly different form , containing an ( erroneous ) factor 2 before the Y12 term . However , following ...
Page 23
... equation ( 1869 ) : LW LW AGIW = YLW - YLW - YLW 12 LW AGLW = -2712 LW LW LW LW AG132 = Y12 - 13 - 23 O O [ II - 36 ] [ II - 33A ] [ II - 37 ] LW There is therefore a simple relation between A12 , A121 , A132 on the one hand , and y and ...
... equation ( 1869 ) : LW LW AGIW = YLW - YLW - YLW 12 LW AGLW = -2712 LW LW LW LW AG132 = Y12 - 13 - 23 O O [ II - 36 ] [ II - 33A ] [ II - 37 ] LW There is therefore a simple relation between A12 , A121 , A132 on the one hand , and y and ...
Contents
1 | |
9 | |
19 | |
25 | |
5 Electrical Double Layer Interactions | 51 |
6 Brownian Movement ForcesOsmotic Interactions of Polymers | 71 |
7 Rate of Decay with Distance | 79 |
8 Lifshitzvan der Waals and Lewis AcidBase Properties of Liquid WaterPhysical and PhysicoChemical Effects | 93 |
16 Direct Measurement Methods Treating the Force Balance in Particular | 203 |
17 Surface Tension Components and Parameters of Liquids and Solids | 213 |
Hydrophobic Interactions | 227 |
Hydrophilic InteractionsOsmotic Pressures of PEO Solutions | 243 |
20 The Primary and Secondary Interactions | 263 |
21 Phase Separation in Polymer Solutions Coacervation and Complex Coacervation | 275 |
22 Solubility of Polymers and Other Solutes | 297 |
23 Cell and Particle Stability | 319 |
9 Role of Water in Hydrophobic Attraction | 101 |
10 Role of Water in Hydrophilic Repulsion | 109 |
11 The WaterAir Interface | 117 |
12 Contact Angleand Surface Tension Determination and Preparation of Solid Surfaces | 131 |
13 Interfacial Tension DeterminationInfluence of Macroscopic and MicroscopicScale Interactions | 157 |
14 Different Approaches for Interpreting Contact Angles and Determining the Surface Tension and Surface Tension Components of Solids | 165 |
15 Electrokinetic Methods | 179 |
24 Adsorption and Adhesion in Aqueous Media Including LigandReceptor Interactions | 345 |
25 Kinetics and Energetics of Protein Adsorption onto Metal Oxide Surfaces | 385 |
List of Symbols Used | 399 |
References | 407 |
Index | 431 |
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Common terms and phrases
adhesion adsorbed adsorption AGAB AGiwi AGLW antibodies approach aqueous media aqueous solution biopolymers C-potential cells Chapter XIX Chem coacervation Colloid Colloid Interface Sci complex coacervation compounds concentration contact angle contact angle measurements decay decrease Derjaguin determined dextran dissolved distance Docoslis electron-donor electrophoresis electrophoretic mobility electrostatic energy of cohesion energy of interaction epitope equation erythrocytes flocculation formamide free energy Giese glycerol human serum albumin hydration hydrophilic hydrophobic attraction immersed in water interaction energy interfacial tension ionic strength isoelectric Israelachvili Lewis acid-base low-energy LW LW LW macromolecules macroscopic-scale materials miscibility mJ/m² moieties molecular weight molecules or particles monopolar Neumann obtained occur Overbeek parameter paratope phase separation polar liquids polymer polymer molecules protein solid surface solubility solvent specific stability surface tension surface tension components surfactant Table temperature water molecules water-air interface whilst zero