Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page 28
... mixture of two polar substances 1 and 2 two temperature-independent terms are added to Equation (1-33) to give the total dipolar interaction energy: E : _ 2 “12,1'22 _ I'LIZaZ _ “ZZa'l 3kT r126 r126 r126 Dispersion force is the name ...
... mixture of two polar substances 1 and 2 two temperature-independent terms are added to Equation (1-33) to give the total dipolar interaction energy: E : _ 2 “12,1'22 _ I'LIZaZ _ “ZZa'l 3kT r126 r126 r126 Dispersion force is the name ...
Page 35
... mixture leaving the bubbler or saturator is then equal to the vapor pressure of the liquid. Almost 100 years ago, Trouton pointed out the existence of some interesting regularities in the heats of vaporization of liquids. For many ...
... mixture leaving the bubbler or saturator is then equal to the vapor pressure of the liquid. Almost 100 years ago, Trouton pointed out the existence of some interesting regularities in the heats of vaporization of liquids. For many ...
Page 43
... 0.339 Aniline 4.40 3.15 2.37 1.85 1.51 Mercury 1.55 1.50 1.45 1.41 1.37 1-13 it is seen that the viscosity coefficient increases with. n-Octane 0.542 0.483 0.433 — 0.355 1. A mixture of gases containing 24.0 g of C0,,. 1-12 VISCOSITY 43.
... 0.339 Aniline 4.40 3.15 2.37 1.85 1.51 Mercury 1.55 1.50 1.45 1.41 1.37 1-13 it is seen that the viscosity coefficient increases with. n-Octane 0.542 0.483 0.433 — 0.355 1. A mixture of gases containing 24.0 g of C0,,. 1-12 VISCOSITY 43.
Page 44
... mixtures, the presence of significant attractive interactions between molecules of different components is often reflected in a viscosity larger than that expected on the basis of additivity, but the detailed interpretation of such ...
... mixtures, the presence of significant attractive interactions between molecules of different components is often reflected in a viscosity larger than that expected on the basis of additivity, but the detailed interpretation of such ...
Page 47
... mixture model was developed by G. Nemethy and H. A. Scheraga. Emphasis is on the equilibrium number of hydrogen bonds that exist in the liquid, a number related to cluster size, for water molecules on the outside of a cluster have but ...
... mixture model was developed by G. Nemethy and H. A. Scheraga. Emphasis is on the equilibrium number of hydrogen bonds that exist in the liquid, a number related to cluster size, for water molecules on the outside of a cluster have but ...
Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero