Physical Principles and Techniques of Protein Chemistry Part C, Part 3Sydney Leach Physical Principles and Techniques of Protein Chemistry, Part C focuses on the effects of intermolecular interactions that are transmitted between ligands and proteins and from protein to protein. This book discusses the density and volume change measurements; direct volume change; osmotic pressure; and small-angle X-ray scattering. The theory of particulate scattering; pulsed nuclear magnetic resonance; absorption of water by diamagnetic molecules; and use of least squares in data analysis are also elaborated. This text likewise covers the iteration process; optical rotatory dispersion and the main chain conformation of proteins; and basic relations for optically active molecules. Other topics include the circular dichroism, secondary structure of proteins, visible rotatory dispersion, and peptide cotton effects. This publication is intended for protein chemists, but is also useful to biologists, medical practitioners, and students researching on protein chemistry. |
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Page 77
... i excluded volume between closest approach of two centers of mass grams Of component i per kilogram of water 1A selection of readings which is minimally sufficient to provide 77 Chapter 18. Osmotic Pressure Glossary of Symbols.
... i excluded volume between closest approach of two centers of mass grams Of component i per kilogram of water 1A selection of readings which is minimally sufficient to provide 77 Chapter 18. Osmotic Pressure Glossary of Symbols.
Page 78
... osmotic equilibrium osmotic pressure density apparent specific volume of component i I. Introduction and Phenomenon The measurement of osmotic pressure can be employed as a routine method for the thermodynamic study of many kinds of ...
... osmotic equilibrium osmotic pressure density apparent specific volume of component i I. Introduction and Phenomenon The measurement of osmotic pressure can be employed as a routine method for the thermodynamic study of many kinds of ...
Page 79
... osmotic pressure with the molecular weight M. The quest for unambiguous values of M has not abated and will not be resolved in the near future by the perfunctory use of a single, universally accepted technique. Sharp ... OSMOTIC PRESSURE 79.
... osmotic pressure with the molecular weight M. The quest for unambiguous values of M has not abated and will not be resolved in the near future by the perfunctory use of a single, universally accepted technique. Sharp ... OSMOTIC PRESSURE 79.
Page 80
... osmotic pressure given in Section II, a description of the phenomenon is proposed at this point. It is hoped by this means to ease the path of the unprepared student when he is confronted with thermodynamic formalism”; it is also ...
... osmotic pressure given in Section II, a description of the phenomenon is proposed at this point. It is hoped by this means to ease the path of the unprepared student when he is confronted with thermodynamic formalism”; it is also ...
Page 81
... osmotic pressure utilizing a U-tube with limbs A and B separated by a semipermeable membrane. (a) Equilibrium with ... pressure equal to the osmotic pressure is applied before any net transport of water can take place after adding the ...
... osmotic pressure utilizing a U-tube with limbs A and B separated by a semipermeable membrane. (a) Equilibrium with ... pressure equal to the osmotic pressure is applied before any net transport of water can take place after adding the ...
Contents
1 | |
77 | |
Chapter 19 SmallAngle Xray Scattering | 141 |
Chapter 20 Pulsed Nuclear Magnetic Resonance | 245 |
Chapter 21 The Use of Least Squares in Data Analysis | 301 |
Chapter 22 Optical Rotatory Dispersion and the Main Chain Conformation of Proteins | 357 |
Chapter 23 Circular Dichroism | 445 |
Author Index | 595 |
Subject Index | 609 |
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Common terms and phrases
a-helix absorption acid Amer angle B-structure Beychok Biochem Biochemistry Biol Blout calculated CD band CD spectra Chem chromophore circular dichroism coefficient Cohn coil concentration conformation constant contribution Cotton effects creatine kinase cross-section defined definition denatured determined dialyzate diffusible components dipole disulfide electron density ellipticity enzyme equation equilibrium exciton experimental Fasman field find first fit function grams helix hemoglobin intensity interaction Kratky lysozyme magnetic measurements membrane method molal mole molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve osmotic pressure parameters partial specific volume peptide Phys Pilz polymer polypeptides positive protein protein solution Pysh radius of gyration random coil residues ribonuclease rotational strength rotatory sample scattering curve Schellman Section shape significant small-angle solvent solvent medium spectrum studies subunits sufficiently temperature theoretical theory Tinoco tion transition tyrosine wavelength Woody X-ray zero