ADVANCES IN INORGANIC CHEMISTRY AND RADIOCHEMISTRY VOL 2

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Advances in Inorganic Chemistry and Radiochemistry

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CONTENTS

Contributors

Chapter 1. Stereochemistry of Ionic Solids

I. Introduction

II. Ionic Coordination Polyhedra

III. Simple Ionic Compounds

IV. The Influence of Crystal Fields on Transition-Metal Stereochemistry

V. Stereochemistry of B-Subgroup Ions

VI. Small Ion Distortions and "Rattling"

VII. Conclusions

VIII. Appendix: Ionic Radii

References

Chapter 2. Organometallic Compounds

I. Introduction

II. New Preparative Techniques and Procedures. III. Structure and Bonding in Organometallic Compounds

IV. Reactivity and Reaction Pathways of Organometallic Compounds

V. Applications of Organometallic Reagents in Research and Technology

VI. Present Trends in Organometallic Research

List of Symbols

References

Chapter 3. Fluorine-Containing Compounds of Sulfur

I. Introduction

II. Fluorides of Sulfur

III. Sulfur Oxyhalides Containing Fluorine

IV. Fluorooxyacids of Sulfur

V. Other Inorganic Compounds Containing Sulfur and Fluorine

VI. Compounds Containing Carbon, Sulfur, Fluorine, and Elements other than Oxygen. VII. Perfluoroalkanesulfonic Acids, Their Anhydrides, Salts, and Esters

VIII. Certain Compounds Containing the-(SO2)-Bridge

References

Chapter 4. Amides and Imides of the Oxyacids of Sulfur

I. Introduction

II. Sulfur Imides Derived from Oxides of Sulfur in Oxidation States between (0) and (III)

III. Sulfur Imides Derived from Sulfur Dioxide

IV. Amides of Oxyacids of Sulfur (IV)

V. Sulfur Imides Derived from Sulfur Trioxide

VI. Amides of Oxyacids of Sulfur (VI)

References

Chapter 5. Halides of the Actinide Elements

I. Introduction. II. Survey of the Actinide Element Halides

III. Preparative

IV. Properties of Halides

References

Chapter 6. Structures of Compounds Containing Chains of Sulfur Atoms

I. Introduction

II. Elemental Sulfur

III. The Polysulfide Ions

IV. The Sulfur Hydrides and Halides

V. Organic Disulfides and Polysulfides

VI. Sulfur Chains Terminated by Cyano Groups

VII. Sulfur Chains Terminated by Sulfonyl Groups

VIII. Sulfur Chains Terminated by Sulfonate Groups: The Polythionates

IX. Unsymmetrical Compounds

X. Comments on Structural Evidence

XI. Stereochemistry