Front cover image for Membrane Electrodes

Membrane Electrodes

Membrane Electrodes considers the significant developments in the field of sensing probes, with an emphasis on membrane electrodes. This book is organized into three parts encompassing 11 chapters. Part I is an introduction to the variety of ion-selective membrane electrodes that have been constructed and with which experiments have been conducted. This part deals first with the thermodynamic principles and other concepts underlying the description of the behavior of electrolyte solutions, followed by a discussion on the various theories of membrane potential applicable to a variety of sol
eBook, English, 2014
Elsevier Science, Saint Louis, 2014
1 online resource (379 pages)
9780323153294, 0323153291
1044724969
Front Cover; Membrane Electrodes; Copyright Page; Table of Contents; Preface; Part I: Introduction and Theory; Chapter 1. Introduction; References; Chapter 2. Electrochemistry of Aqueous Electrolyte Solutions; A. Free Energy; B. Chemical Potential; C. Condition for Equilibrium between Two Phases; D. Activity and Activity Coefficient; E. Mean Activity of the Electrolyte; F. Osmotic Coefficient; G. The Debye-Hiickel Theory; H. Mixture of Electrolyte and Nonelectrolyte; I. Mixture of Two Electrolytes; References; Chapter 3. Theories of Membrane Electrode Potentials; A. Reversible Electrodes. B. Relation between Free Energy and Potential of a Galvanic CellC. Standard Potentials; D. Concentration Cell without Transference; E. Concentration Cell with Transference; F. Liquid Junction or Diffusion Potential: General Equation; G. Diffusion Potential between Two Solutions of the Same Electrolyte; H. Diffusion Equations; I. Principles Underlying Membrane Electrode Behavior; References; Part II: Solid and Liquid Membrane Electrodes; Chapter 4. Organic Ion Exchangers; A. Properties of Ion Exchange Membranes; B. Some Experimental Results. C. Properties and Applications of Asymmetric Membrane ElectrodesReferences; Chapter 5. Electrodes Selective to Halide Ions; A. Preparation of the Membrane Electrode and Formation of the Membrane Cell; B. Ion Activity Standards; C. Determination of Selectivity Constants (MUoot Ij); D. Properties and Applications of Fluoride-Selective Electrodes; E. Properties and Applications of Halide-Selective Membrane Electrodes; References; Chapter 6. Electrodes Selective to Other Anions; A. Preparation of Membrane Electrodes; B. Cyanide-Selective Membrane Electrodes. C. Sulfide-Selective Membrane ElectrodesD. Membrane Electrodes Selective to Other Anions; References; Chapter 7. Electrodes Selective to Cations; A. Preparation of Electrodes; B. Ammonium-Selective Membrane Electrodes; C. Cadmium-Selective Membrane Electrodes; D. Calcium-Selective Membrane Electrodes; E. Cesium-Selective Membrane Electrodes; F. Copper-Selective Membrane Electrodes; G. Iron-Selective Membrane Electrodes; H. Lead-Selective Membrane Electrodes; I. Potassium-Selective Membrane Electrodes; J. Silver-Selective Membrane Electrodes; K. Sodium-Selective Membrane Electrodes. L. Thallium-Selective Membrane ElectrodesM. Uranyl Ion-Selective Membrane Electrodes; References; Chapter 8. Liquid Membrane Electrodes; A. Macrocyclic Compounds; B. Cation-Selective Liquid Membrane Electrodes; C. Anion-Selective Liquid Membrane Electrodes; References; Part III: Glass and Other Related Membrane Electrodes; Chapter 9. Glass Membrane Electrodes; A. Structure and Resistance of Glasses; B. Glasses for the Measurement of Ion Activities; C. Properties of Glass Electrodes; D. Electrical Impedance of Glass Electrodes; E. Glass Membrane Potentials
F. Electrode Responses in Aqueous-Nonaqueous Solvents